Global Look-Up Table of Physiological Ratios for the Real-Time Adjustment of Chlorophyll-a Fluorescence within the OneArgo Framework

This dataset provides a global Look-Up Table (LUT) of physiological ratios for the real-time adjustment of chlorophyll-a fluorescence measured by biogeochemical Argo (BGC-Argo) profiling floats. The physiological ratios aim to account for the global variability in the relationship between fluorescence and chlorophyll-a concentration, as influenced by phytoplankton physiology. The LUT was developed using two different gap-filled observational Argo-based products (SOCA machine learning-based methodology ; Sauzède et al., 2016; Sauzède et al., 2024). The first product provides gap-filled chlorophyll-a data derived from fluorescence corrected for dark signal and non-photochemical quenching (NPQ) following Schmechtig et al. (2023), while the second product provides chlorophyll-a concentrations derived from light attenuation. The latter is based on the downward irradiance at 490 nm (ED490) derived from the SOCA-light method (Renosh et al., 2023). From this, the diffuse attenuation coefficient (KD490) is computed, which is subsequently used to estimate the chlorophyll-a concentration through the bio-optical relationships described by Morel et al. (2007). These two products, based on fluorescence and radiometry, enable the derivation of spatially varying correction factors, or physiological ratios. These ratios provide a validated grounded framework for adjusting real-time fluorescence observations from OneArgo floats into chlorophyll-a concentrations. The LUT is distributed in NetCDF format and is provided on a regular 1°×1° latitude–longitude grid covering the global ocean. Each grid cell contains the temporal mean, averaged over the water column (from the surface to 1.5 times the euphotic depth), of the physiological ratio. The file also includes metadata describing variable definitions, units, and other relevant information. Variables included: - physiological_ratio — fluorescence-to-radiometry-based chlorophyll correction factor (dimensionless) - lat, lon — spatial coordinates (degrees north/east) - Global attributes — dataset description, reference citation, and contact information