'''DEFINITION''' Ocean acidification is quantified by decreases in pH, which is a measure of acidity: a decrease in pH value means an increase in acidity, that is, acidification. The observed decrease in ocean pH resulting from increasing concentrations of CO2 is an important indicator of global change. The estimate of global mean pH builds on a reconstruction methodology, * Obtain values for alkalinity based on the so called “locally interpolated alkalinity regression (LIAR)” method after Carter et al., 2016; 2018. * Build on surface ocean partial pressure of carbon dioxide (CMEMS product: MULTIOBS_GLO_BIO_CARBON_SURFACE_REP_015_008) obtained from an ensemble of Feed-Forward Neural Networks (Chau et al. 2022) which exploit sampling data gathered in the Surface Ocean CO2 Atlas (SOCAT) (https://www.socat.info/) * Derive a gridded field of ocean surface pH based on the van Heuven et al., (2011) CO2 system calculations using reconstructed pCO2 (MULTIOBS_GLO_BIO_CARBON_SURFACE_REP_015_008) and alkalinity. The global mean average of pH at yearly time steps is then calculated from the gridded ocean surface pH field. It is expressed in pH unit on total hydrogen ion scale. In the figure, the amplitude of the uncertainty (1σ ) of yearly mean surface sea water pH varies at a range of (0.0023, 0.0029) pH unit (see Quality Information Document for more details). The trend and uncertainty estimates amount to -0.0017±0.0004e-1 pH units per year. The indicator is derived from in situ observations of CO2 fugacity (SOCAT data base, www.socat.info, Bakker et al., 2016). These observations are still sparse in space and time. Monitoring pH at higher space and time resolutions, as well as in coastal regions will require a denser network of observations and preferably direct pH measurements. A full discussion regarding this OMI can be found in section 2.10 of the Ocean State Report 4 (Gehlen et al., 2020). '''CONTEXT''' The decrease in surface ocean pH is a direct consequence of the uptake by the ocean of carbon dioxide. It is referred to as ocean acidification. The International Panel on Climate Change (IPCC) Workshop on Impacts of Ocean Acidification on Marine Biology and Ecosystems (2011) defined Ocean Acidification as “a reduction in the pH of the ocean over an extended period, typically decades or longer, which is caused primarily by uptake of carbon dioxide from the atmosphere, but can also be caused by other chemical additions or subtractions from the ocean”. The pH of contemporary surface ocean waters is already 0.1 lower than at pre-industrial times and an additional decrease by 0.33 pH units is projected over the 21st century in response to the high concentration pathway RCP8.5 (Bopp et al., 2013). Ocean acidification will put marine ecosystems at risk (e.g. Orr et al., 2005; Gehlen et al., 2011; Kroeker et al., 2013). The monitoring of surface ocean pH has become a focus of many international scientific initiatives (http://goa-on.org/) and constitutes one target for SDG14 (https://sustainabledevelopment.un.org/sdg14). '''CMEMS KEY FINDINGS''' Since the year 1985, global ocean surface pH is decreasing at a rate of -0.0017±0.0004e-1 per year. '''DOI (product):''' https://doi.org/10.48670/moi-00224

'''DEFINITION''' The global yearly ocean CO2 sink represents the ocean uptake of CO2 from the atmosphere computed over the whole ocean. It is expressed in PgC per year. The ocean monitoring index is presented for the period 1985 to year-1. The yearly estimate of the ocean CO2 sink corresponds to the mean of a 100-member ensemble of CO2 flux estimates (Chau et al. 2022). The range of an estimate with the associated uncertainty is then defined by the empirical 68% interval computed from the ensemble. '''CONTEXT''' Since the onset of the industrial era in 1750, the atmospheric CO2 concentration has increased from about 277±3 ppm (Joos and Spahni, 2008) to 412.44±0.1 ppm in 2020 (Dlugokencky and Tans, 2020). By 2011, the ocean had absorbed approximately 28 ± 5% of all anthropogenic CO2 emissions, thus providing negative feedback to global warming and climate change (Ciais et al., 2013). The ocean CO2 sink is evaluated every year as part of the Global Carbon Budget (Friedlingstein et al. 2022). The uptake of CO2 occurs primarily in response to increasing atmospheric levels. The global flux is characterized by a significant variability on interannual to decadal time scales largely in response to natural climate variability (e.g., ENSO) (Friedlingstein et al. 2022, Chau et al. 2022). '''CMEMS KEY FINDINGS''' The rate of change of the integrated yearly surface downward flux has increased by 0.04±0.03e-1 PgC/yr2 over the period 1985 to year-1. The yearly flux time series shows a plateau in the 90s followed by an increase since 2000 with a growth rate of 0.06±0.04e-1 PgC/yr2. In 2021 (resp. 2020), the global ocean CO2 sink was 2.41±0.13 (resp. 2.50±0.12) PgC/yr. The average over the full period is 1.61±0.10 PgC/yr with an interannual variability (temporal standard deviation) of 0.46 PgC/yr. In order to compare these fluxes to Friedlingstein et al. (2022), the estimate of preindustrial outgassing of riverine carbon of 0.61 PgC/yr, which is in between the estimate by Jacobson et al. (2007) (0.45±0.18 PgC/yr) and the one by Resplandy et al. (2018) (0.78±0.41 PgC/yr) needs to be added. A full discussion regarding this OMI can be found in section 2.10 of the Ocean State Report 4 (Gehlen et al., 2020) and in Chau et al. (2022). '''DOI (product):''' https://doi.org/10.48670/moi-00223