EMODnet Chemistry aims to provide access to marine chemistry datasets and derived data products concerning eutrophication, acidity and contaminants. The importance of the selected substances and other parameters relates to the Marine Strategy Framework Directive (MSFD). This aggregated dataset contains all unrestricted EMODnet Chemistry data on eutrophication and acidity, and covers the Northeast Atlantic Ocean (40W). Data were aggregated and quality controlled by 'IFREMER / IDM / SISMER - Scientific Information Systems for the SEA' in France. ITS-90 water temperature and water body salinity variables have also been included ('as are') to complete the eutrophication and acidity data. If you use these variables for calculations, please refer to SeaDataNet for the quality flags: https://www.seadatanet.org/Products/Aggregated-datasets. Regional datasets concerning eutrophication and acidity are automatically harvested, and the resulting collections are aggregated and quality controlled using ODV Software and following a common methodology for all sea regions ( https://doi.org/10.13120/8xm0-5m67). Parameter names are based on P35 vocabulary, which relates to EMODnet Chemistry aggregated parameter names and is available at: https://vocab.nerc.ac.uk/search_nvs/P35/. When not present in original data, water body nitrate plus nitrite was calculated by summing all nitrate and nitrite parameters. The same procedure was applied for water body dissolved inorganic nitrogen (DIN), which was calculated by summing all nitrate, nitrite, and ammonium parameters. Concentrations per unit mass were converted to a unit volume using a constant density of 1.025 kg/L. The aggregated dataset can also be downloaded as an ODV collection and spreadsheet, which is composed of a metadata header followed by tab separated values. This spreadsheet can be imported to ODV Software for visualisation (more information can be found at: https://www.seadatanet.org/Software/ODV).

'''This product has been archived''' For operationnal and online products, please visit https://marine.copernicus.eu '''Short description:''' For the North Atlantic and Arctic oceans, the ESA Ocean Colour CCI Remote Sensing Reflectance (merged, bias-corrected Rrs) data are used to compute surface Chlorophyll (mg m-3, 1 km resolution) using the regional OC5CCI chlorophyll algorithm. The Rrs are generated by merging the data from SeaWiFS, MODIS-Aqua, MERIS, VIIRS and OLCI-3A sensors and realigning the spectra to that of the MERIS sensor. The algorithm used is OC5CCI - a variation of OC5 (Gohin et al., 2002) developed by IFREMER in collaboration with PML. As part of this development, an OC5CCI look up table was generated specifically for application over OC- CCI merged daily remote sensing reflectances. The resulting OC5CCI algorithm was tested and selected through an extensive calibration exercise that analysed the quantitative performance against in situ data for several algorithms in these specific regions. Phytoplankton functional types (PFT) dataset provides daily chlorophyll concentrations of 5 phytoplankton groups: nano-, pico-, micro-phytoplankton, diatoms and dinoflagellates. Micro consists of the sum of diatoms and dinoflagellates. L3 products are daily files, while the L4 are monthly composites. ESA-CCI Rrs raw data are provided by PML. These are processed to produce chlorophyll concentration using the same in-house software as in the operational processing. Ocean colour technique exploits the emerging electromagnetic radiation from the sea surface in different wavelengths. The spectral variability of this signal defines the so called ocean colour which is affected by the presence of phytoplankton. By comparing reflectances at different wavelengths and calibrating the result against in-situ measurements, an estimate of chlorophyll content can be derived. '''Processing information:''' ESA OC-CCI Rrs raw data are provided by Plymouth Marine Laboratory, currently at 4km resolution globally. These are processed to produce chlorophyll concentration using the same in-house software as in the operational processing. The entire CCI data set is consistent and processing is done in one go. Both OC CCI and the REP product are versioned. Standard masking criteria for detecting clouds or other contamination factors have been applied during the generation of the Rrs, i.e., land, cloud, sun glint, atmospheric correction failure, high total radiance, large solar zenith angle (70deg), large spacecraft zenith angle (56deg), coccolithophores, negative water leaving radiance, and normalized water leaving radiance at 560 nm 0.15 Wm-2 sr-1 (McClain et al., 1995). For the regional products, a variant of the OC-CCI chain is run to produce high resolution data at the 1km resolution necessary. A detailed description of the ESA OC-CCI processing system can be found in OC-CCI (2014e). '''Description of observation methods/instruments:''' Ocean colour technique exploits the emerging electromagnetic radiation from the sea surface in different wavelengths. The spectral variability of this signal defines the so called ocean colour which is affected by the presence of phytoplankton. By comparing reflectances at different wavelengths and calibrating the result against in-situ measurements, an estimate of chlorophyll content can be derived. '''Quality / Accuracy / Calibration information:''' Detailed description of cal/val is given in the relevant QUID, associated validation reports and quality documentation. '''Suitability, Expected type of users / uses:''' This product is meant for use for educational purposes and for the managing of the marine safety, marine resources, marine and coastal environment and for climate and seasonal studies. '''DOI (product) :''' https://doi.org/10.48670/moi-00071

Seasonal Climatology of Chlorophyll-a for Loire River for the period 1976-2020 and for the following seasons: - winter: January-March, - spring: April-June, - summer: July-September, - autumn: October-December Observational data span from 1976 to 2020. Depth levels (m): -125.0, -100.0, -75.0, -50.0,-40.0, -30.0, -25.0, -20.0, -15.0, -10.0, -8.0, -6.0, -4.0, -2.0, -0.0 Data Sources: observational data from SeaDataNet/EMODNet Chemistry Data Network. Description of DIVAnd analysis: The computation was done with DIVAnd (Data-Interpolating Variational Analysis in n dimensions), version 2.7.4, using GEBCO 30sec topography for the spatial connectivity of water masses. The horizontal resolution of the produced DIVAnd maps grids is 0.01 degrees. Correlation length was optimized and filtered vertically and a seasonally-averaged profile was used. Signal to noise ratio was fixed to 1 for vertical profiles and to 0.1 for time series to account for the redundancy in the time series observations. Logarithmic transformation applied to the data prior to the analysis. Background field: the data mean value is subtracted from the data. . Detrending of data: no, Advection constraint applied: no. Units: mg/m^3.

'''DEFINITION''' The regional annual chlorophyll anomaly is computed by subtracting a reference climatology (1997-2014) from the annual chlorophyll mean, on a pixel-by-pixel basis and in log10 space. Both the annual mean and the climatology are computed employing the regional products as distributed by CMEMS, derived by application of the regional chlorophyll algorithms over remote sensing reflectances (Rrs) produced by the Plymouth Marine Laboratory (PML) using the ESA Ocean Colour Climate Change Initiative processor (ESA OC-CCI, Sathyendranath et al., 2018a). '''CONTEXT''' Phytoplankton and chlorophyll concentration as their proxy respond rapidly to changes in their physical environment. In the Mediterranean Sea, these changes are seasonal and are mostly determined by light and nutrient availability (Gregg and Rousseaux, 2014). By comparing annual mean values to the climatology, we effectively remove the seasonal signal at each grid point, while retaining information on peculiar events during the year. In particular, chlorophyll anomalies in the Mediterranean Sea can then be correlated with the North Atlantic Oscillation (NAO) and El Niño Southern Oscillation (ENSO) (Basterretxea et al 2018, Colella et al 2016). '''CMEMS KEY FINDINGS''' The 2019 average chlorophyll anomaly in the Mediterranean Sea is 1.02 mg m-3 (0.005 in log10 [mg m-3]), with a maximum value of 73 mg m-3 (1.86 log10 [mg m-3]) and a minimum value of 0.04 mg m-3 (-1.42 log10 [mg m-3]). The overall east west divided pattern reported in 2016, showing negative anomalies for the Western Mediterranean Sea and positive anomalies for the Levantine Sea (Sathyendranath et al., 2018b) is modified in 2019, with a widespread positive anomaly all over the eastern basin, which reaches the western one, up to the offshore water at the west of Sardinia. Negative anomaly values occur in the coastal areas of the basin and in some sectors of the Alboràn Sea. In the northwestern Mediterranean the values switch to be positive again in contrast to the negative values registered in 2017 anomaly. The North Adriatic Sea shows a negative anomaly offshore the Po river, but with weaker value with respect to the 2017 anomaly map.

This product displays the stations present in EMODnet validated dataset where naphthalene levels have been measured in sediment. EMODnet Chemistry has included the gathering of contaminants data since the beginning of the project in 2009. For the maps for EMODnet Chemistry Phase III, it was requested to plot data per matrix (water,sediment, biota), per biological entity and per chemical substance. The series of relevant map products have been developed according to the criteria D8C1 of the MSFD Directive, specifically focusing on the requirements under the new Commission Decision 2017/848 (17th May 2017). The Commission Decision points to relevant threshold values that are specified in the WFD, as well as relating how these contaminants should be expressed (units and matrix etc.) through the related Directives i.e. Priority substances for Water. EU EQS Directive does not fix any threshold values in sediments. On the contrary Regional Sea Conventions provide some of them, and these values have been taken into account for the development of the visualization products. To produce the maps the following process has been followed: 1. Data collection through SeaDataNet standards (CDI+ODV) 2. Harvesting, harmonization, validation and P01 code decomposition of data 3. SQL query on data sets from point 2 4. Production of map with each point representing at least one record that match the criteria The harmonization of all the data has been the most challenging task considering the heterogeneity of the data sources, sampling protocols. Preliminary processing were necessary to harmonize all the data : • For water: contaminants in the dissolved phase; • For sediment: data on total sediment (regardless of size class) or size class < 2000 μm • For biota: contaminant data will focus on molluscs, on fish (only in the muscle), and on crustaceans • Exclusion of data values equal to 0

This gridded product visualizes 1960 - 2014 water body nitrate concentration (umol/l) in the North Sea domain, for each season (winter: December – February; spring: March – May; summer: June – August; autumn: September – November). It is produced as a Diva 4D analysis, version 4.6.9: a reference field of all seasonal data between 1960-2014 was used; results were logit transformed to avoid negative/underestimated values in the interpolated results; error threshold masks L1 (0.3) and L2 (0.5) are included as well as the unmasked field. Every step of the time dimension corresponds to a 10-year moving average for each season. The depth dimension allows visualizing the gridded field at various depths.

Moving 10-years analysis of Oxygen at Northeast Atlantic Ocean for each season: - winter: January-March, - spring: April-June, - summer: July-September, - autumn: October-December. Every year of the time dimension corresponds to the 10-year centred average of each season. Decades span from 1963-1972 until 2005-2014. Observational data span from 1963 to 2014. Depth range (IODE standard depths): -3000.0, -2500.0, -2000.0, -1750, -1500.0, -1400.0, -1300.0, -1200.0, -1100.0, -1000.0, -900.0, -800.0, -700.0, -600.0, -500.0, -400.0, -300.0, -250.0, -200.0, -150.0, -125.0, -100.0, -75.0, -50.0,-40.0, -30.0, -20.0, -10.0, -5.0, -0.0 Data Sources: observational data from SeaDataNet/EMODNet Chemistry Data Network. Description of DIVA analysis: Geostatistical data analysis by DIVA (Data-Interpolating Variational Analysis) tool. GEBCO 1min topography is used for the contouring preparation. Analyzed filed masked using relative error threshold 0.3 and 0.5 DIVA settings. Signal to noise ratio and correlation length were optimized and filtered vertically and a seasonally-averaged profile was used. Background field: the data mean value is subtracted from the data. Detrending of data: no, Advection consraint applied: no. Units: umol/l

This product displays the stations where fluoranthene has been measured and the values present in EMODnet Chemistry infrastructure are either above or below the limit of detection or quantification (LOD/LOQ), i.e for the substance, in that station, quality values found in EMODnet validated dataset can be equal to 6, Q or 1. It is necessary to take into account that LOD/LOQ can change with time. These products aggregate data by station, producing only one final value for each station (above, below or above/below). EMODnet Chemistry has included the gathering of contaminants data since the beginning of the project in 2009. For the maps for EMODnet Chemistry Phase III, it was requested to plot data per matrix (water,sediment, biota), per biological entity and per chemical substance. The series of relevant map products have been developed according to the criteria D8C1 of the MSFD Directive, specifically focusing on the requirements under the new Commission Decision 2017/848 (17th May 2017). The Commission Decision points to relevant threshold values that are specified in the WFD, as well as relating how these contaminants should be expressed (units and matrix etc.) through the related Directives i.e. Priority substances for Water. EU EQS Directive does not fix any threshold values in sediments. On the contrary Regional Sea Conventions provide some of them, and these values have been taken into account for the development of the visualization products. To produce the maps the following process has been followed: 1. Data collection through SeaDataNet standards (CDI+ODV) 2. Harvesting, harmonization, validation and P01 code decomposition of data 3. SQL query on data sets from point 2 4. Production of map with each point representing at least one record that match the criteria The harmonization of all the data has been the most challenging task considering the heterogeneity of the data sources, sampling protocols. Preliminary processing were necessary to harmonize all the data : • For water: contaminants in the dissolved phase; • For sediment: data on total sediment (regardless of size class) or size class < 2000 μm • For biota: contaminant data will focus on molluscs, on fish (only in the muscle), and on crustaceans • Exclusion of data values equal to 0

This product displays the stations present in EMODnet validated dataset where cadmium levels have been measured in sediment. EMODnet Chemistry has included the gathering of contaminants data since the beginning of the project in 2009. For the maps for EMODnet Chemistry Phase III, it was requested to plot data per matrix (water,sediment, biota), per biological entity and per chemical substance. The series of relevant map products have been developed according to the criteria D8C1 of the MSFD Directive, specifically focusing on the requirements under the new Commission Decision 2017/848 (17th May 2017). The Commission Decision points to relevant threshold values that are specified in the WFD, as well as relating how these contaminants should be expressed (units and matrix etc.) through the related Directives i.e. Priority substances for Water. EU EQS Directive does not fix any threshold values in sediments. On the contrary Regional Sea Conventions provide some of them, and these values have been taken into account for the development of the visualization products. To produce the maps the following process has been followed: 1. Data collection through SeaDataNet standards (CDI+ODV) 2. Harvesting, harmonization, validation and P01 code decomposition of data 3. SQL query on data sets from point 2 4. Production of map with each point representing at least one record that match the criteria The harmonization of all the data has been the most challenging task considering the heterogeneity of the data sources, sampling protocols. Preliminary processing were necessary to harmonize all the data : • For water: contaminants in the dissolved phase; • For sediment: data on total sediment (regardless of size class) or size class < 2000 μm • For biota: contaminant data will focus on molluscs, on fish (only in the muscle), and on crustaceans • Exclusion of data values equal to 0

This visualization product displays the type of litter in percent per net per year from research and monitoring protocols. EMODnet Chemistry included the collection of marine litter in its 3rd phase. Before 2021, there was no coordinated effort at the regional or European scale for micro-litter. Given this situation, EMODnet Chemistry proposed to adopt the data gathering and data management approach as generally applied for marine data, i.e., populating metadata and data in the CDI Data Discovery and Access service using dedicated SeaDataNet data transport formats. EMODnet Chemistry is currently the official EU collector of micro-litter data from Marine Strategy Framework Directive (MSFD) National Monitoring activities (descriptor 10). A series of specific standard vocabularies or standard terms related to micro-litter have been added to SeaDataNet NVS (NERC Vocabulary Server) Common Vocabularies to describe the micro-litter. European micro-litter data are collected by the National Oceanographic Data Centres (NODCs). Micro-litter map products are generated from NODCs data after a test of the aggregated collection including data and data format checks and data harmonization. A filter is applied to represent only micro-litter sampled according to research and monitoring protocols as MSFD monitoring. To calculate percentages for each type, formula applied is: Type (%) = (∑number of particles of each type)*100 / (∑number of particles of all type) When the number of micro-litters was not filled or was equal zero, it was not possible to calculate the percentage. Standard vocabularies for micro-litter types are taken from Seadatanet's H01 library (https://vocab.seadatanet.org/v_bodc_vocab_v2/search.asp?lib=H01 ). Some morphological types of micro-litters may have been sampled but were not defined by the protocole applied during the survey. They are represented as « undefined micro-litter items ». Warnings: - the absence of data on the map does not necessarily mean that they do not exist, but that no information has been entered in the National Oceanographic Data Centre (NODC) for this area. - since 03/07/2023, the preferred label « Undefined micro-litter items » has been integrated into the H01 library whereas the labels « microplastic items », « non-plastic man-made micro-particles (e.g. glass, metal, tar) » and «non-plastic filaments (natural fibres, rubber) » have been deprecated. When defined, the material or polymer type can be checked directly in the source data.