'''DEFINITION''' Ocean acidification is quantified by decreases in pH, which is a measure of acidity: a decrease in pH value means an increase in acidity, that is, acidification. The observed decrease in ocean pH resulting from increasing concentrations of CO2 is an important indicator of global change. The estimate of global mean pH builds on a reconstruction methodology, * Obtain values for alkalinity based on the so called “locally interpolated alkalinity regression (LIAR)” method after Carter et al., 2016; 2018. * Build on surface ocean partial pressure of carbon dioxide (CMEMS product: MULTIOBS_GLO_BIO_CARBON_SURFACE_REP_015_008) obtained from an ensemble of Feed-Forward Neural Networks (Chau et al. 2022) which exploit sampling data gathered in the Surface Ocean CO2 Atlas (SOCAT) (https://www.socat.info/) * Derive a gridded field of ocean surface pH based on the van Heuven et al., (2011) CO2 system calculations using reconstructed pCO2 (MULTIOBS_GLO_BIO_CARBON_SURFACE_REP_015_008) and alkalinity. The global mean average of pH at yearly time steps is then calculated from the gridded ocean surface pH field. It is expressed in pH unit on total hydrogen ion scale. In the figure, the amplitude of the uncertainty (1σ ) of yearly mean surface sea water pH varies at a range of (0.0023, 0.0029) pH unit (see Quality Information Document for more details). The trend and uncertainty estimates amount to -0.0017±0.0004e-1 pH units per year. The indicator is derived from in situ observations of CO2 fugacity (SOCAT data base, www.socat.info, Bakker et al., 2016). These observations are still sparse in space and time. Monitoring pH at higher space and time resolutions, as well as in coastal regions will require a denser network of observations and preferably direct pH measurements. A full discussion regarding this OMI can be found in section 2.10 of the Ocean State Report 4 (Gehlen et al., 2020). '''CONTEXT''' The decrease in surface ocean pH is a direct consequence of the uptake by the ocean of carbon dioxide. It is referred to as ocean acidification. The International Panel on Climate Change (IPCC) Workshop on Impacts of Ocean Acidification on Marine Biology and Ecosystems (2011) defined Ocean Acidification as “a reduction in the pH of the ocean over an extended period, typically decades or longer, which is caused primarily by uptake of carbon dioxide from the atmosphere, but can also be caused by other chemical additions or subtractions from the ocean”. The pH of contemporary surface ocean waters is already 0.1 lower than at pre-industrial times and an additional decrease by 0.33 pH units is projected over the 21st century in response to the high concentration pathway RCP8.5 (Bopp et al., 2013). Ocean acidification will put marine ecosystems at risk (e.g. Orr et al., 2005; Gehlen et al., 2011; Kroeker et al., 2013). The monitoring of surface ocean pH has become a focus of many international scientific initiatives (http://goa-on.org/) and constitutes one target for SDG14 (https://sustainabledevelopment.un.org/sdg14). '''CMEMS KEY FINDINGS''' Since the year 1985, global ocean surface pH is decreasing at a rate of -0.0017±0.019 decade-1 '''DOI (product):''' https://doi.org/10.48670/moi-00224

'''This product has been archived''' For operationnal and online products, please visit https://marine.copernicus.eu '''DEFINITION''' Oligotrophic subtropical gyres are regions of the ocean with low levels of nutrients required for phytoplankton growth and low levels of surface chlorophyll-a whose concentration can be quantified through satellite observations. The gyre boundary has been defined using a threshold value of 0.15 mg m-3 chlorophyll for the Atlantic gyres (Aiken et al. 2016), and 0.07 mg m-3 for the Pacific gyres (Polovina et al. 2008). The area inside the gyres for each month is computed using monthly chlorophyll data from which the monthly climatology is subtracted to compute anomalies. A gap filling algorithm has been utilized to account for missing data. Trends in the area anomaly are then calculated for the entire study period (September 1997 to December 2020). '''CONTEXT''' Oligotrophic gyres of the oceans have been referred to as ocean deserts (Polovina et al. 2008). They are vast, covering approximately 50% of the Earth’s surface (Aiken et al. 2016). Despite low productivity, these regions contribute significantly to global productivity due to their immense size (McClain et al. 2004). Even modest changes in their size can have large impacts on a variety of global biogeochemical cycles and on trends in chlorophyll (Signorini et al. 2015). Based on satellite data, Polovina et al. (2008) showed that the areas of subtropical gyres were expanding. The Ocean State Report (Sathyendranath et al. 2018) showed that the trends had reversed in the Pacific for the time segment from January 2007 to December 2016. '''CMEMS KEY FINDINGS''' The trend in the North Atlantic gyre area for the 1997 Sept – 2020 December period was positive, with a 0.39% year-1 increase in area relative to 2000-01-01 values. This trend has decreased compared with the 1997-2019 trend of 0.45%, and is statistically significant (p<0.05). During the 1997 Sept – 2020 December period, the trend in chlorophyll concentration was positive (0.24% year-1) inside the North Atlantic gyre relative to 2000-01-01 values. This time series extension has resulted in a reversal in the rate of change, compared with the -0.18% trend for the 1997-209 period and is statistically significant (p<0.05). Note: The key findings will be updated annually in November, in line with OMI evolutions. '''DOI (product):''' https://doi.org/10.48670/moi-00226

'''This product has been archived''' For operationnal and online products, please visit https://marine.copernicus.eu '''Short description:''' For the '''Global''' Ocean '''Satellite Observations''', ACRI-ST company (Sophia Antipolis, France) is providing '''Chlorophyll-a''' and '''Optics''' products [1997 - present] based on the '''Copernicus-GlobColour''' processor. * '''Chlorophyll and Bio''' products refer to Chlorophyll-a, Primary Production (PP) and Phytoplankton Functional types (PFT). Products are based on a multi sensors/algorithms approach to provide to end-users the best estimate. Two dailies Chlorophyll-a products are distributed: ** one limited to the daily observations (called L3), ** the other based on a space-time interpolation: the '''Cloud Free''' (called L4). * '''Optics''' products refer to Reflectance (RRS), Suspended Matter (SPM), Particulate Backscattering (BBP), Secchi Transparency Depth (ZSD), Diffuse Attenuation (KD490) and Absorption Coef. (ADG/CDM). * The spatial resolution is 4 km. For Chlorophyll, a 1 km over the Atlantic (46°W-13°E , 20°N-66°N) is also available for the '''Cloud Free''' product, plus a 300m Global coastal product (OLCI S3A & S3B merged). *Products (Daily, Monthly and Climatology) are based on the merging of the sensors SeaWiFS, MODIS, MERIS, VIIRS-SNPP&JPSS1, OLCI-S3A&S3B. Additional products using only OLCI upstreams are also delivered. * Recent products are organized in datasets called NRT (Near Real Time) and long time-series in datasets called REP/MY (Multi-Year). The NRT products are provided one day after satellite acquisition and updated a few days after in Delayed Time (DT) to provide a better quality. An uncertainty is given at pixel level for all products. To find the '''Copernicus-GlobColour''' products in the catalogue, use the search keyword '''GlobColour'''. See [http://catalogue.marine.copernicus.eu/documents/QUID/CMEMS-OC-QUID-009-030-032-033-037-081-082-083-085-086-098.pdf QUID document] for a detailed description and assessment. '''DOI (product) :''' https://doi.org/10.48670/moi-00075

'''DEFINITION''' The Mediterranean water mass formation rates are evaluated in 4 areas as defined in the Ocean State Report issue 2 (OSR2, von Schuckmann et al., 2018) section 3.4 (Simoncelli and Pinardi, 2018): (1) the Gulf of Lions for the Western Mediterranean Deep Waters (WMDW); (2) the Southern Adriatic Sea Pit for the Eastern Mediterranean Deep Waters (EMDW); (3) the Cretan Sea for Cretan Intermediate Waters (CIW) and Cretan Deep Waters (CDW); (4) the Rhodes Gyre, the area of formation of the so-called Levantine Intermediate Waters (LIW) and Levantine Deep Waters (LDW). Annual water mass formation rates have been computed using daily mixed layer depth estimates (density criteria Δσ = 0.01 kg/m3, 10 m reference level) considering the annual maximum volume of water above mixed layer depth with potential density within or higher the specific thresholds specified in Table 1 then divided by seconds per year. Annual mean values are provided using the Mediterranean 1/24o eddy resolving reanalysis (Escudier et al. 2020, 2021). Time spans from 1987 to the year preceding the current one [-1Y], operationally extended yearly. '''CONTEXT''' The formation of intermediate and deep water masses is one of the most important processes occurring in the Mediterranean Sea, being a component of its general overturning circulation. This circulation varies at interannual and multidecadal time scales and it is composed of an upper zonal cell (Zonal Overturning Circulation) and two main meridional cells in the western and eastern Mediterranean (Pinardi and Masetti 2000). The objective is to monitor the main water mass formation events using the eddy resolving Mediterranean Sea Reanalysis (MEDSEA_MULTIYEAR_PHY_006_004, Escudier et al. 2020, 2021) and considering Pinardi et al. (2015) and Simoncelli and Pinardi (2018) as references for the methodology. The Mediterranean Sea Reanalysis can reproduce both Eastern Mediterranean Transient and Western Mediterranean Transition phenomena and catches the principal water mass formation events reported in the literature. This will permit constant monitoring of the open ocean deep convection process in the Mediterranean Sea and a better understanding of the multiple drivers of the general overturning circulation at interannual and multidecadal time scales. Deep and intermediate water formation events reveal themselves by a deep mixed layer depth distribution in four Mediterranean areas: Gulf of Lions, Southern Adriatic Sea Pit, Cretan Sea and Rhodes Gyre. '''KEY FINDINGS''' The Western Mediterranean Deep Water (WMDW) formation events in the Gulf of Lion appear to be larger after 1999 consistently with Schroeder et al. (2006, 2008) related to the Eastern Mediterranean Transient event. This modification of WMDW after 2005 has been called Western Mediterranean Transition. WMDW formation events are consistent with Somot et al. (2016) and the event in 2009 is also reported in Houpert et al. (2016). The Eastern Mediterranean Deep Water (EMDW) formation in the Southern Adriatic Pit region displays a period of water mass formation between 1988 and 1993, in agreement with Pinardi et al. (2015), in 1996, 1999 and 2000 as documented by Manca et al. (2002). Weak deep water formation in winter 2006 is confirmed by observations in Vilibić and Šantić (2008). An intense deep water formation event is detected in 2012-2013 (Gačić et al., 2014). Last years are characterized by large events starting from 2017 (Mihanovic et al., 2021). Cretan Intermediate Water formation rates present larger peaks between 1989 and 1993 with the ones in 1992 and 1993 composing the Eastern Mediterranean Transient phenomena. The Cretan Deep Water formed in 1992 and 1993 is characterized by the highest densities of the entire period in accordance with Velaoras et al. (2014). The Levantine Deep Water formation rate in the Rhode Gyre region presents the largest values between 1992 and 1993 in agreement with Kontoyiannis et al. (1999). '''DOI (product):''' https://doi.org/10.48670/mds-00318

'''DEFINITION''' We have derived an annual eutrophication and eutrophication indicator map for the North Atlantic Ocean using satellite-derived chlorophyll concentration. Using the satellite-derived chlorophyll products distributed in the regional North Atlantic CMEMS MY Ocean Colour dataset (OC- CCI), we derived P90 and P10 daily climatologies. The time period selected for the climatology was 1998-2017. For a given pixel, P90 and P10 were defined as dynamic thresholds such as 90% of the 1998-2017 chlorophyll values for that pixel were below the P90 value, and 10% of the chlorophyll values were below the P10 value. To minimise the effect of gaps in the data in the computation of these P90 and P10 climatological values, we imposed a threshold of 25% valid data for the daily climatology. For the 20-year 1998-2017 climatology this means that, for a given pixel and day of the year, at least 5 years must contain valid data for the resulting climatological value to be considered significant. Pixels where the minimum data requirements were met were not considered in further calculations. We compared every valid daily observation over 2021 with the corresponding daily climatology on a pixel-by-pixel basis, to determine if values were above the P90 threshold, below the P10 threshold or within the [P10, P90] range. Values above the P90 threshold or below the P10 were flagged as anomalous. The number of anomalous and total valid observations were stored during this process. We then calculated the percentage of valid anomalous observations (above/below the P90/P10 thresholds) for each pixel, to create percentile anomaly maps in terms of % days per year. Finally, we derived an annual indicator map for eutrophication levels: if 25% of the valid observations for a given pixel and year were above the P90 threshold, the pixel was flagged as eutrophic. Similarly, if 25% of the observations for a given pixel were below the P10 threshold, the pixel was flagged as oligotrophic. '''CONTEXT''' Eutrophication is the process by which an excess of nutrients – mainly phosphorus and nitrogen – in a water body leads to increased growth of plant material in an aquatic body. Anthropogenic activities, such as farming, agriculture, aquaculture and industry, are the main source of nutrient input in problem areas (Jickells, 1998; Schindler, 2006; Galloway et al., 2008). Eutrophication is an issue particularly in coastal regions and areas with restricted water flow, such as lakes and rivers (Howarth and Marino, 2006; Smith, 2003). The impact of eutrophication on aquatic ecosystems is well known: nutrient availability boosts plant growth – particularly algal blooms – resulting in a decrease in water quality (Anderson et al., 2002; Howarth et al.; 2000). This can, in turn, cause death by hypoxia of aquatic organisms (Breitburg et al., 2018), ultimately driving changes in community composition (Van Meerssche et al., 2019). Eutrophication has also been linked to changes in the pH (Cai et al., 2011, Wallace et al. 2014) and depletion of inorganic carbon in the aquatic environment (Balmer and Downing, 2011). Oligotrophication is the opposite of eutrophication, where reduction in some limiting resource leads to a decrease in photosynthesis by aquatic plants, reducing the capacity of the ecosystem to sustain the higher organisms in it. Eutrophication is one of the more long-lasting water quality problems in Europe (OSPAR ICG-EUT, 2017), and is on the forefront of most European Directives on water-protection. Efforts to reduce anthropogenically-induced pollution resulted in the implementation of the Water Framework Directive (WFD) in 2000. '''CMEMS KEY FINDINGS''' The coastal and shelf waters, especially between 30 and 400N that showed active oligotrophication flags for 2020 have reduced in 2021 and a reversal to eutrophic flags can be seen in places. Again, the eutrophication index is positive only for a small number of coastal locations just north of 40oN in 2021, however south of 40oN there has been a significant increase in eutrophic flags, particularly around the Azores. In general, the 2021 indicator map showed an increase in oligotrophic areas in the Northern Atlantic and an increase in eutrophic areas in the Southern Atlantic. The Third Integrated Report on the Eutrophication Status of the OSPAR Maritime Area (OSPAR ICG-EUT, 2017) reported an improvement from 2008 to 2017 in eutrophication status across offshore and outer coastal waters of the Greater North Sea, with a decrease in the size of coastal problem areas in Denmark, France, Germany, Ireland, Norway and the United Kingdom. '''DOI (product):''' https://doi.org/10.48670/moi-00195

'''DEFINITION''' The OMI_EXTREME_SL_NORTHWESTSHELF_slev_mean_and_anomaly_obs indicator is based on the computation of the 99th and the 1st percentiles from in situ data (observations). It is computed for the variable sea level measured by tide gauges along the coast. The use of percentiles instead of annual maximum and minimum values, makes this extremes study less affected by individual data measurement errors. The annual percentiles referred to annual mean sea level are temporally averaged and their spatial evolution is displayed in the dataset omi_extreme_sl_northwestshelf_slev_mean_and_anomaly_obs, jointly with the anomaly in the target year. This study of extreme variability was first applied to sea level variable (Pérez Gómez et al 2016) and then extended to other essential variables, sea surface temperature and significant wave height (Pérez Gómez et al 2018). '''CONTEXT''' Sea level (SLEV) is one of the Essential Ocean Variables most affected by climate change. Global mean sea level rise has accelerated since the 1990’s (Abram et al., 2019, Legeais et al., 2020), due to the increase of ocean temperature and mass volume caused by land ice melting (WCRP, 2018). Basin scale oceanographic and meteorological features lead to regional variations of this trend that combined with changes in the frequency and intensity of storms could also rise extreme sea levels up to one metre by the end of the century (Vousdoukas et al., 2020, Tebaldi et al., 2021). This will significantly increase coastal vulnerability to storms, with important consequences on the extent of flooding events, coastal erosion and damage to infrastructures caused by waves (Boumis et al., 2023). The increase in extreme sea levels over recent decades is, therefore, primarily due to the rise in mean sea level. Note, however, that the methodology used to compute this OMI removes the annual 50th percentile, thereby discarding the mean sea level trend to isolate changes in storminess. The North West Shelf area presents positive sea level trends with higher trend estimates in the German Bight and around Denmark, and lower trends around the southern part of Great Britain (Dettmering et al., 2021). '''COPERNICUS MARINE SERVICE KEY FINDINGS''' The completeness index criteria is fulfilled by 33 stations in 2023, one less than in 2022 (32). The mean 99th percentiles present a large spatial variability related to the tidal pattern, with largest values found in East England and at the entrance of the English channel, and lowest values along the Danish and Swedish coasts, ranging from the 3.08 m above mean sea level in Immingan (East England) to 0.45 m above mean sea level in Tregde (Norway). The standard deviation of annual 99th percentiles ranges between 2-3 cm in the western part of the region (e.g.: 2 cm in Harwich, 3 cm in Dunkerke) and 7-8 cm in the eastern part and the Kattegat (e.g. 8 cm in Stenungsund, Sweden). The 99th percentile anomalies for 2023 show overall slightly negative values except in the Kattegat (Eastern part), with maximum significant values of +11 cm in Hornbaek (Denmark), and +10 cm in Ringhals (Sweden). '''DOI (product):''' https://doi.org/10.48670/moi-00272

'''Short description:''' You can find here the biogeochemistry non assimilative hindcast simulation GLOBAL_REANALYSIS_BIO_001_018 at 1/4° over period 1998 - 2016. Outputs are delivered as monthly mean files with Netcdf format (CF/COARDS 1.5 convention) on the native tripolar grid (ORCA025) at ¼° resolution with 75 vertical levels. This simulation is based on the PISCES biogeochemical model. It is forced offline at a daily frequency by the equivalent of the GLOBAL-REANALYSIS-PHYS-001-009 physics product but without data assimilation. '''Detailed description: ''' There are 8 different datasets: * dataset-global-nahindcast-bio-001-018-no3 containing : nitrate concentration * dataset-global-nahindcast-bio-001-018-po4 containing : phosphate concentration * dataset-global-nahindcast-bio-001-018-si containing : silicate concentration * dataset-global-nahindcast-bio-001-018-o2 containing : dissolved oxygen concentration * dataset-global-nahindcast-bio-001-018-fe containing : iron concentration * dataset-global-nahindcast-bio-001-018-chl containing : chlorophyll concentration * dataset-global-nahindcast-bio-001-018-phyc containing : carbon phytoplankton biomass * dataset-global-nahindcast-bio-001-018-pp containing : primary production The horizontal grid is the standard ORCA025 tri-polar grid (1440 x 1021 grid points). The three poles are located over Antarctic, Central Asia and North Canada. The ¼ degree resolution corresponds to the equator. The vertical grid has 75 levels, with a resolution of 1 meter near the surface and 200 meters in the deep ocean.Biogeochemical and physical simulations start at rest (cold start) in December 1991. The spin-up period consists of 5 years of interannual simulation between 1992 and 1997. The simulation period covers the ocean color era (1998 – 2016).The biogeochemical model used is PISCES (Aumont, in prep). It is a model of intermediate complexity designed for global ocean applications (Aumont and Bopp, 2006) and is part of NEMO modeling platform. It has 24 prognostic variables and simulates biogeochemical cycles of oxygen, carbon and the main nutrients controlling phytoplankton growth (nitrate, ammonium, phosphate, silicic acid and iron). The model distinguishes four plankton functional types based on size: two phytoplankton groups <nowiki>(small = nanophytoplankton and large = diatoms)</nowiki> and two zooplankton groups <nowiki>(small = microzooplankton and large = mesozooplankton).</nowiki>Prognostic variables of phytoplankton are total biomass in C, Fe, Si (for diatoms) and chlorophyll and hence the Fe/C, Si/C, Chl/C ratios are variable. For zooplankton, all these ratios are constant and total biomass in C is the only prognostic variable. The bacterial pool is not modeled explicitly. PISCES distinguishes three non-living pools for organic carbon: small particulate organic carbon, big particulate organic carbon and semi-labile dissolved organic carbon. While the C/N/P composition of dissolved and particulate matter is tied to Redfield stoichiometry, the iron, silicon and carbonate contents of the particles are computed prognostically. Next to the three organic detrital pools, carbonate and biogenic siliceous particles are modeled. Besides, the model simulates dissolved inorganic carbon and total alkalinity. In PISCES, phosphate and nitrate + ammonium are linked by constant Redfield ratio <nowiki>(C/N/P = 122/16/1)</nowiki>, but cycles of phosphorus and nitrogen are decoupled by nitrogen fixation and denitrification. Biogeochemical model PISCES (NEMO3.5) is forced offline by daily fields of the physical model NEMO (OPA module in the NEMO platform) without any assimilation of physical data. The main features of this dynamical ocean are: * NEMO 3.1 * Atmospheric forcings from 3-hourly ERA-Interim reanalysis products, CORE bulk formulation * Vertical diffusivity coefficient is computed by solving the TKE equation * Tidal mixing is parameterized according to the works of Bessières et al. (2008) and Koch-Larrouy et al, (2006). * Sea-Ice model: LIM2 with the Elastic-Viscous-Plastic rheology * Initial conditions: Levitus 98 climatology for temperature and salinity, patched with PHC2.1 for the Arctic regions, and Medatlas for the Mediterranean Sea. A special treatment is done on vertical diffusivity coefficient (Kz): the daily mean is done on Log10(Kz) after a filtering of enhanced convection (Kz increased artificially to 10 m2.s-1 when the water column is unstable). The purpose of this Log10 is to average the orders of magnitudes and to give more weight to small values of vertical diffusivity. The atmospheric forcing fields are daily averages from ERA-Interim reanalysis product (CORE bulk formulation). Boundary fluxes account for nutrient supply from three different sources: Atmospheric deposition (Aumont et al., 2008), rivers for nutrients, dissolved inorganic carbon and alkalinity (Ludwig et al., 1996; Mayorga et al., 2010) and inputs of Fe from marine sediments. Nutrient and freshwater inflows by rivers are colocalized. River and dust inputs are balanced with sediment trapping of NO3, Si and Carbon. An annual and global value of atmospheric carbon dioxide is imposed at sea surface.