'''DEFINITION''' Ocean acidification is quantified by decreases in pH, which is a measure of acidity: a decrease in pH value means an increase in acidity, that is, acidification. The observed decrease in ocean pH resulting from increasing concentrations of CO2 is an important indicator of global change. The estimate of global mean pH builds on a reconstruction methodology, * Obtain values for alkalinity based on the so called “locally interpolated alkalinity regression (LIAR)” method after Carter et al., 2016; 2018. * Build on surface ocean partial pressure of carbon dioxide (CMEMS product: MULTIOBS_GLO_BIO_CARBON_SURFACE_REP_015_008) obtained from an ensemble of Feed-Forward Neural Networks (Chau et al. 2022) which exploit sampling data gathered in the Surface Ocean CO2 Atlas (SOCAT) (https://www.socat.info/) * Derive a gridded field of ocean surface pH based on the van Heuven et al., (2011) CO2 system calculations using reconstructed pCO2 (MULTIOBS_GLO_BIO_CARBON_SURFACE_REP_015_008) and alkalinity. The global mean average of pH at yearly time steps is then calculated from the gridded ocean surface pH field. It is expressed in pH unit on total hydrogen ion scale. In the figure, the amplitude of the uncertainty (1σ ) of yearly mean surface sea water pH varies at a range of (0.0023, 0.0029) pH unit (see Quality Information Document for more details). The trend and uncertainty estimates amount to -0.0017±0.0004e-1 pH units per year. The indicator is derived from in situ observations of CO2 fugacity (SOCAT data base, www.socat.info, Bakker et al., 2016). These observations are still sparse in space and time. Monitoring pH at higher space and time resolutions, as well as in coastal regions will require a denser network of observations and preferably direct pH measurements. A full discussion regarding this OMI can be found in section 2.10 of the Ocean State Report 4 (Gehlen et al., 2020). '''CONTEXT''' The decrease in surface ocean pH is a direct consequence of the uptake by the ocean of carbon dioxide. It is referred to as ocean acidification. The International Panel on Climate Change (IPCC) Workshop on Impacts of Ocean Acidification on Marine Biology and Ecosystems (2011) defined Ocean Acidification as “a reduction in the pH of the ocean over an extended period, typically decades or longer, which is caused primarily by uptake of carbon dioxide from the atmosphere, but can also be caused by other chemical additions or subtractions from the ocean”. The pH of contemporary surface ocean waters is already 0.1 lower than at pre-industrial times and an additional decrease by 0.33 pH units is projected over the 21st century in response to the high concentration pathway RCP8.5 (Bopp et al., 2013). Ocean acidification will put marine ecosystems at risk (e.g. Orr et al., 2005; Gehlen et al., 2011; Kroeker et al., 2013). The monitoring of surface ocean pH has become a focus of many international scientific initiatives (http://goa-on.org/) and constitutes one target for SDG14 (https://sustainabledevelopment.un.org/sdg14). '''CMEMS KEY FINDINGS''' Since the year 1985, global ocean surface pH is decreasing at a rate of -0.0017±0.019 decade-1 '''DOI (product):''' https://doi.org/10.48670/moi-00224

'''This product has been archived''' '''DEFINITION''' Estimates of Ocean Heat Content (OHC) are obtained from integrated differences of the measured temperature and a climatology along a vertical profile in the ocean (von Schuckmann et al., 2018). The regional OHC values are then averaged from 60°S-60°N aiming i) to obtain the mean OHC as expressed in Joules per meter square (J/m2) to monitor the large-scale variability and change. ii) to monitor the amount of energy in the form of heat stored in the ocean (i.e. the change of OHC in time), expressed in Watt per square meter (W/m2). Ocean heat content is one of the six Global Climate Indicators recommended by the World Meterological Organisation for Sustainable Development Goal 13 implementation (WMO, 2017). '''CONTEXT''' Knowing how much and where heat energy is stored and released in the ocean is essential for understanding the contemporary Earth system state, variability and change, as the ocean shapes our perspectives for the future (von Schuckmann et al., 2020). Variations in OHC can induce changes in ocean stratification, currents, sea ice and ice shelfs (IPCC, 2019; 2021); they set time scales and dominate Earth system adjustments to climate variability and change (Hansen et al., 2011); they are a key player in ocean-atmosphere interactions and sea level change (WCRP, 2018) and they can impact marine ecosystems and human livelihoods (IPCC, 2019). '''CMEMS KEY FINDINGS''' Regional trends for the period 2005-2019 from the Copernicus Marine Service multi-ensemble approach show warming at rates ranging from the global mean average up to more than 8 W/m2 in some specific regions (e.g. northern hemisphere western boundary current regimes). There are specific regions where a negative trend is observed above noise at rates up to about -5 W/m2 such as in the subpolar North Atlantic, or the western tropical Pacific. These areas are characterized by strong year-to-year variability (Dubois et al., 2018; Capotondi et al., 2020). Note: The key findings will be updated annually in November, in line with OMI evolutions. '''DOI (product):''' https://doi.org/10.48670/moi-00236

'''This product has been archived''' For operationnal and online products, please visit https://marine.copernicus.eu '''DEFINITION''' Oligotrophic subtropical gyres are regions of the ocean with low levels of nutrients required for phytoplankton growth and low levels of surface chlorophyll-a whose concentration can be quantified through satellite observations. The gyre boundary has been defined using a threshold value of 0.15 mg m-3 chlorophyll for the Atlantic gyres (Aiken et al. 2016), and 0.07 mg m-3 for the Pacific gyres (Polovina et al. 2008). The area inside the gyres for each month is computed using monthly chlorophyll data from which the monthly climatology is subtracted to compute anomalies. A gap filling algorithm has been utilized to account for missing data. Trends in the area anomaly are then calculated for the entire study period (September 1997 to December 2020). '''CONTEXT''' Oligotrophic gyres of the oceans have been referred to as ocean deserts (Polovina et al. 2008). They are vast, covering approximately 50% of the Earth’s surface (Aiken et al. 2016). Despite low productivity, these regions contribute significantly to global productivity due to their immense size (McClain et al. 2004). Even modest changes in their size can have large impacts on a variety of global biogeochemical cycles and on trends in chlorophyll (Signorini et al. 2015). Based on satellite data, Polovina et al. (2008) showed that the areas of subtropical gyres were expanding. The Ocean State Report (Sathyendranath et al. 2018) showed that the trends had reversed in the Pacific for the time segment from January 2007 to December 2016. '''CMEMS KEY FINDINGS''' The trend in the North Atlantic gyre area for the 1997 Sept – 2020 December period was positive, with a 0.39% year-1 increase in area relative to 2000-01-01 values. This trend has decreased compared with the 1997-2019 trend of 0.45%, and is statistically significant (p<0.05). During the 1997 Sept – 2020 December period, the trend in chlorophyll concentration was positive (0.24% year-1) inside the North Atlantic gyre relative to 2000-01-01 values. This time series extension has resulted in a reversal in the rate of change, compared with the -0.18% trend for the 1997-209 period and is statistically significant (p<0.05). Note: The key findings will be updated annually in November, in line with OMI evolutions. '''DOI (product):''' https://doi.org/10.48670/moi-00226

'''This product has been archived''' For operationnal and online products, please visit https://marine.copernicus.eu '''Short description:''' For the '''Global''' Ocean '''Satellite Observations''', ACRI-ST company (Sophia Antipolis, France) is providing '''Chlorophyll-a''' and '''Optics''' products [1997 - present] based on the '''Copernicus-GlobColour''' processor. * '''Chlorophyll and Bio''' products refer to Chlorophyll-a, Primary Production (PP) and Phytoplankton Functional types (PFT). Products are based on a multi sensors/algorithms approach to provide to end-users the best estimate. Two dailies Chlorophyll-a products are distributed: ** one limited to the daily observations (called L3), ** the other based on a space-time interpolation: the '''Cloud Free''' (called L4). * '''Optics''' products refer to Reflectance (RRS), Suspended Matter (SPM), Particulate Backscattering (BBP), Secchi Transparency Depth (ZSD), Diffuse Attenuation (KD490) and Absorption Coef. (ADG/CDM). * The spatial resolution is 4 km. For Chlorophyll, a 1 km over the Atlantic (46°W-13°E , 20°N-66°N) is also available for the '''Cloud Free''' product, plus a 300m Global coastal product (OLCI S3A & S3B merged). *Products (Daily, Monthly and Climatology) are based on the merging of the sensors SeaWiFS, MODIS, MERIS, VIIRS-SNPP&JPSS1, OLCI-S3A&S3B. Additional products using only OLCI upstreams are also delivered. * Recent products are organized in datasets called NRT (Near Real Time) and long time-series in datasets called REP/MY (Multi-Year). The NRT products are provided one day after satellite acquisition and updated a few days after in Delayed Time (DT) to provide a better quality. An uncertainty is given at pixel level for all products. To find the '''Copernicus-GlobColour''' products in the catalogue, use the search keyword '''GlobColour'''. See [http://catalogue.marine.copernicus.eu/documents/QUID/CMEMS-OC-QUID-009-030-032-033-037-081-082-083-085-086-098.pdf QUID document] for a detailed description and assessment. '''DOI (product) :''' https://doi.org/10.48670/moi-00075

'''DEFINITION''' The Mediterranean water mass formation rates are evaluated in 4 areas as defined in the Ocean State Report issue 2 (OSR2, von Schuckmann et al., 2018) section 3.4 (Simoncelli and Pinardi, 2018): (1) the Gulf of Lions for the Western Mediterranean Deep Waters (WMDW); (2) the Southern Adriatic Sea Pit for the Eastern Mediterranean Deep Waters (EMDW); (3) the Cretan Sea for Cretan Intermediate Waters (CIW) and Cretan Deep Waters (CDW); (4) the Rhodes Gyre, the area of formation of the so-called Levantine Intermediate Waters (LIW) and Levantine Deep Waters (LDW). Annual water mass formation rates have been computed using daily mixed layer depth estimates (density criteria Δσ = 0.01 kg/m3, 10 m reference level) considering the annual maximum volume of water above mixed layer depth with potential density within or higher the specific thresholds specified in Table 1 then divided by seconds per year. Annual mean values are provided using the Mediterranean 1/24o eddy resolving reanalysis (Escudier et al. 2020, 2021). Time spans from 1987 to the year preceding the current one [-1Y], operationally extended yearly. '''CONTEXT''' The formation of intermediate and deep water masses is one of the most important processes occurring in the Mediterranean Sea, being a component of its general overturning circulation. This circulation varies at interannual and multidecadal time scales and it is composed of an upper zonal cell (Zonal Overturning Circulation) and two main meridional cells in the western and eastern Mediterranean (Pinardi and Masetti 2000). The objective is to monitor the main water mass formation events using the eddy resolving Mediterranean Sea Reanalysis (MEDSEA_MULTIYEAR_PHY_006_004, Escudier et al. 2020, 2021) and considering Pinardi et al. (2015) and Simoncelli and Pinardi (2018) as references for the methodology. The Mediterranean Sea Reanalysis can reproduce both Eastern Mediterranean Transient and Western Mediterranean Transition phenomena and catches the principal water mass formation events reported in the literature. This will permit constant monitoring of the open ocean deep convection process in the Mediterranean Sea and a better understanding of the multiple drivers of the general overturning circulation at interannual and multidecadal time scales. Deep and intermediate water formation events reveal themselves by a deep mixed layer depth distribution in four Mediterranean areas: Gulf of Lions, Southern Adriatic Sea Pit, Cretan Sea and Rhodes Gyre. '''KEY FINDINGS''' The Western Mediterranean Deep Water (WMDW) formation events in the Gulf of Lion appear to be larger after 1999 consistently with Schroeder et al. (2006, 2008) related to the Eastern Mediterranean Transient event. This modification of WMDW after 2005 has been called Western Mediterranean Transition. WMDW formation events are consistent with Somot et al. (2016) and the event in 2009 is also reported in Houpert et al. (2016). The Eastern Mediterranean Deep Water (EMDW) formation in the Southern Adriatic Pit region displays a period of water mass formation between 1988 and 1993, in agreement with Pinardi et al. (2015), in 1996, 1999 and 2000 as documented by Manca et al. (2002). Weak deep water formation in winter 2006 is confirmed by observations in Vilibić and Šantić (2008). An intense deep water formation event is detected in 2012-2013 (Gačić et al., 2014). Last years are characterized by large events starting from 2017 (Mihanovic et al., 2021). Cretan Intermediate Water formation rates present larger peaks between 1989 and 1993 with the ones in 1992 and 1993 composing the Eastern Mediterranean Transient phenomena. The Cretan Deep Water formed in 1992 and 1993 is characterized by the highest densities of the entire period in accordance with Velaoras et al. (2014). The Levantine Deep Water formation rate in the Rhode Gyre region presents the largest values between 1992 and 1993 in agreement with Kontoyiannis et al. (1999). '''DOI (product):''' https://doi.org/10.48670/mds-00318