'''DEFINITION''' Ocean acidification is quantified by decreases in pH, which is a measure of acidity: a decrease in pH value means an increase in acidity, that is, acidification. The observed decrease in ocean pH resulting from increasing concentrations of CO2 is an important indicator of global change. The estimate of global mean pH builds on a reconstruction methodology, * Obtain values for alkalinity based on the so called “locally interpolated alkalinity regression (LIAR)” method after Carter et al., 2016; 2018. * Build on surface ocean partial pressure of carbon dioxide (CMEMS product: MULTIOBS_GLO_BIO_CARBON_SURFACE_REP_015_008) obtained from an ensemble of Feed-Forward Neural Networks (Chau et al. 2022) which exploit sampling data gathered in the Surface Ocean CO2 Atlas (SOCAT) (https://www.socat.info/) * Derive a gridded field of ocean surface pH based on the van Heuven et al., (2011) CO2 system calculations using reconstructed pCO2 (MULTIOBS_GLO_BIO_CARBON_SURFACE_REP_015_008) and alkalinity. The global mean average of pH at yearly time steps is then calculated from the gridded ocean surface pH field. It is expressed in pH unit on total hydrogen ion scale. In the figure, the amplitude of the uncertainty (1σ ) of yearly mean surface sea water pH varies at a range of (0.0023, 0.0029) pH unit (see Quality Information Document for more details). The trend and uncertainty estimates amount to -0.0017±0.0004e-1 pH units per year. The indicator is derived from in situ observations of CO2 fugacity (SOCAT data base, www.socat.info, Bakker et al., 2016). These observations are still sparse in space and time. Monitoring pH at higher space and time resolutions, as well as in coastal regions will require a denser network of observations and preferably direct pH measurements. A full discussion regarding this OMI can be found in section 2.10 of the Ocean State Report 4 (Gehlen et al., 2020). '''CONTEXT''' The decrease in surface ocean pH is a direct consequence of the uptake by the ocean of carbon dioxide. It is referred to as ocean acidification. The International Panel on Climate Change (IPCC) Workshop on Impacts of Ocean Acidification on Marine Biology and Ecosystems (2011) defined Ocean Acidification as “a reduction in the pH of the ocean over an extended period, typically decades or longer, which is caused primarily by uptake of carbon dioxide from the atmosphere, but can also be caused by other chemical additions or subtractions from the ocean”. The pH of contemporary surface ocean waters is already 0.1 lower than at pre-industrial times and an additional decrease by 0.33 pH units is projected over the 21st century in response to the high concentration pathway RCP8.5 (Bopp et al., 2013). Ocean acidification will put marine ecosystems at risk (e.g. Orr et al., 2005; Gehlen et al., 2011; Kroeker et al., 2013). The monitoring of surface ocean pH has become a focus of many international scientific initiatives (http://goa-on.org/) and constitutes one target for SDG14 (https://sustainabledevelopment.un.org/sdg14). '''CMEMS KEY FINDINGS''' Since the year 1985, global ocean surface pH is decreasing at a rate of -0.0017±0.019 decade-1 '''DOI (product):''' https://doi.org/10.48670/moi-00224

'''Short description:''' This product consists of 3D fields of Particulate Organic Carbon (POC), Particulate Backscattering coefficient (bbp), Chlorophyll-a concentration (Chla), Downwelling Photosynthetic Available Radiation (PAR) and downwelling irradiance, at 0.25°x0.25° resolution from the surface to 1000 m. A neural network estimates the vertical distribution of Chla and bbp from surface ocean color measurements with hydrological properties and additional drivers. The SOCA-light models is used to integrate light. '''DOI (product):''' https://doi.org/10.48670/moi-00046

'''DEFINITION''' The global annual chlorophyll anomaly is computed by subtracting a reference climatology (1997-2014) from the annual chlorophyll mean, on a pixel-by-pixel basis and in log10 space. Both the annual mean and the climatology are computed employing ESA Ocean Colour Climate Change Initiative (ESA OC-CCI, Sathyendranath et al., 2018a) global products (i.e. using the standard OC-CCI chlorophyll algorithms, OCI) as distributed by CMEMS. '''CONTEXT''' Phytoplankton – and chlorophyll concentration as a proxy for phytoplankton – respond rapidly to changes in their physical environment. Some of those changes are seasonal and are determined by light and nutrient availability (Racault et al., 2012). By comparing annual mean values to a climatology, we effectively remove the seasonal signal, while retaining information on potential events during the year. Chlorophyll anomalies can be correlated to climate indexes in particular regions, such as the ENSO index in the equatorial Pacific (Behrenfeld et al. 2006; Racault et al., 2012) and the IOD index in the Indian Ocean (Brewin et al., 2012). It is important to study chlorophyll anomalies in consonance with sea surface temperature and sea level anomalies, as increases in chlorophyll are generally consistent with decreases in SST and sea level anomalies, suggesting an increase in mixing and vertical nutrient transport (von Schuckmann et al., 2016). '''CMEMS KEY FINDINGS''' The average global chlorophyll anomaly 2019 is -0.02 log10(mg m-3), with a maximum value of 1.7 log10(mg m-3) and a minimum value of -3.2 log10(mg m-3). That is to say that, in average, the annual 2019 mean value is slightly lower (96%) than the 1997-2014 climatological value. The positive signals reported in 2016 and 2017 (Sathyendranath et al., 2018b) in the southern Pacific Ocean could still be observed in the 2019 map, while the significant negative anomalies in the tropical waters of the northern Pacific Ocean were also detected to a lesser extent. Areas showing a change of anomaly sign from 2019 include the southern coast of Japan (no anomaly to positive) and the tropical Atlantic (anomalies close to zero for 2019). A marked increase in chlorophyll concentration was observed during 2019 in the Great Australian Bight, while negative anomalies became stronger in the Guatemala Basin and the region south of the Gulf of Guinea and, with values of chlorophyll reaching as low as 30% of the climatological value (anomaly < -0.5 log10(mg m-3)). The persistent positive anomalies in the higher latitudes of the North Atlantic (> 40°) match the cooling observed in the 2018 and previous years SST anomaly maps.