'''Short description:''' For the '''Global''' Ocean '''Satellite Observations''', Brockmann Consult (BC) is providing '''Bio-Geo_Chemical (BGC)''' products based on the ESA-CCI inputs. * Upstreams: SeaWiFS, MODIS, MERIS, VIIRS-SNPP, OLCI-S3A & OLCI-S3B for the '''""multi""''' products. * Variables: Chlorophyll-a ('''CHL'''). * Temporal resolutions: '''monthly'''. * Spatial resolutions: '''4 km''' (multi). * Recent products are organized in datasets called Near Real Time ('''NRT''') and long time-series (from 1997) in datasets called Multi-Years ('''MY'''). To find these products in the catalogue, use the search keyword '''""ESA-CCI""'''. '''DOI (product) :''' https://doi.org/10.48670/moi-00283

'''This product has been archived''' For operationnal and online products, please visit https://marine.copernicus.eu '''Short description:''' For the Global Ocean- Gridded objective analysis fields of temperature and salinity using profiles from the in-situ near real time database are produced monthly. Objective analysis is based on a statistical estimation method that allows presenting a synthesis and a validation of the dataset, providing a support for localized experience (cruises), providing a validation source for operational models, observing seasonal cycle and inter-annual variability. '''DOI (product) :''' https://doi.org/10.48670/moi-00037

'''DEFINITION''' The regional annual chlorophyll anomaly is computed by subtracting a reference climatology (1997-2014) from the annual chlorophyll mean, on a pixel-by-pixel basis and in log10 space. Both the annual mean and the climatology are computed employing the regional products as distributed by CMEMS, derived by application of the regional chlorophyll algorithms over remote sensing reflectances (Rrs) produced by the Plymouth Marine Laboratory (PML) using the ESA Ocean Colour Climate Change Initiative processor (ESA OC-CCI, Sathyendranath et al., 2018a). '''CONTEXT''' Phytoplankton and chlorophyll concentration as their proxy respond rapidly to changes in their physical environment. In the Mediterranean Sea, these changes are seasonal and are mostly determined by light and nutrient availability (Gregg and Rousseaux, 2014). By comparing annual mean values to the climatology, we effectively remove the seasonal signal at each grid point, while retaining information on peculiar events during the year. In particular, chlorophyll anomalies in the Mediterranean Sea can then be correlated with the North Atlantic Oscillation (NAO) and El Niño Southern Oscillation (ENSO) (Basterretxea et al 2018, Colella et al 2016). '''CMEMS KEY FINDINGS''' The 2019 average chlorophyll anomaly in the Mediterranean Sea is 1.02 mg m-3 (0.005 in log10 [mg m-3]), with a maximum value of 73 mg m-3 (1.86 log10 [mg m-3]) and a minimum value of 0.04 mg m-3 (-1.42 log10 [mg m-3]). The overall east west divided pattern reported in 2016, showing negative anomalies for the Western Mediterranean Sea and positive anomalies for the Levantine Sea (Sathyendranath et al., 2018b) is modified in 2019, with a widespread positive anomaly all over the eastern basin, which reaches the western one, up to the offshore water at the west of Sardinia. Negative anomaly values occur in the coastal areas of the basin and in some sectors of the Alboràn Sea. In the northwestern Mediterranean the values switch to be positive again in contrast to the negative values registered in 2017 anomaly. The North Adriatic Sea shows a negative anomaly offshore the Po river, but with weaker value with respect to the 2017 anomaly map.

'''This product has been archived''' For operationnal and online products, please visit https://marine.copernicus.eu '''Short description:''' For the North Atlantic and Arctic oceans, the ESA Ocean Colour CCI Remote Sensing Reflectance (merged, bias-corrected Rrs) data are used to compute surface Chlorophyll (mg m-3, 1 km resolution) using the regional OC5CCI chlorophyll algorithm. The Rrs are generated by merging the data from SeaWiFS, MODIS-Aqua, MERIS, VIIRS and OLCI-3A sensors and realigning the spectra to that of the MERIS sensor. The algorithm used is OC5CCI - a variation of OC5 (Gohin et al., 2002) developed by IFREMER in collaboration with PML. As part of this development, an OC5CCI look up table was generated specifically for application over OC- CCI merged daily remote sensing reflectances. The resulting OC5CCI algorithm was tested and selected through an extensive calibration exercise that analysed the quantitative performance against in situ data for several algorithms in these specific regions. L3 products are daily files, while the L4 are monthly composites. ESA-CCI Rrs raw data are provided by PML. These are processed to produce chlorophyll concentration using the same in-house software as in the operational processing. Ocean colour technique exploits the emerging electromagnetic radiation from the sea surface in different wavelengths. The spectral variability of this signal defines the so called ocean colour which is affected by the presence of phytoplankton. By comparing reflectances at different wavelengths and calibrating the result against in-situ measurements, an estimate of chlorophyll content can be derived. '''Processing information:''' ESA OC-CCI Rrs raw data are provided by Plymouth Marine Laboratory, currently at 4km resolution globally. These are processed to produce chlorophyll concentration using the same in-house software as in the operational processing. The entire CCI data set is consistent and processing is done in one go. Both OC CCI and the REP product are versioned. Standard masking criteria for detecting clouds or other contamination factors have been applied during the generation of the Rrs, i.e., land, cloud, sun glint, atmospheric correction failure, high total radiance, large solar zenith angle (70deg), large spacecraft zenith angle (56deg), coccolithophores, negative water leaving radiance, and normalized water leaving radiance at 560 nm 0.15 Wm-2 sr-1 (McClain et al., 1995). For the regional products, a variant of the OC-CCI chain is run to produce high resolution data at the 1km resolution necessary. A detailed description of the ESA OC-CCI processing system can be found in OC-CCI (2014e). '''Description of observation methods/instruments:''' Ocean colour technique exploits the emerging electromagnetic radiation from the sea surface in different wavelengths. The spectral variability of this signal defines the so called ocean colour which is affected by the presence of phytoplankton. By comparing reflectances at different wavelengths and calibrating the result against in-situ measurements, an estimate of chlorophyll content can be derived. '''Quality / Accuracy / Calibration information:''' Detailed description of cal/val is given in the relevant QUID, associated validation reports and quality documentation. '''Suitability, Expected type of users / uses:''' This product is meant for use for educational purposes and for the managing of the marine safety, marine resources, marine and coastal environment and for climate and seasonal studies. '''DOI (product) :''' https://doi.org/10.48670/moi-00074

'''DEFINITION''' The global yearly ocean CO2 sink represents the ocean uptake of CO2 from the atmosphere computed over the whole ocean. It is expressed in PgC per year. The ocean monitoring index is presented for the period 1985 to year-1. The yearly estimate of the ocean CO2 sink corresponds to the mean of a 100-member ensemble of CO2 flux estimates (Chau et al. 2022). The range of an estimate with the associated uncertainty is then defined by the empirical 68% interval computed from the ensemble. '''CONTEXT''' Since the onset of the industrial era in 1750, the atmospheric CO2 concentration has increased from about 277±3 ppm (Joos and Spahni, 2008) to 412.44±0.1 ppm in 2020 (Dlugokencky and Tans, 2020). By 2011, the ocean had absorbed approximately 28 ± 5% of all anthropogenic CO2 emissions, thus providing negative feedback to global warming and climate change (Ciais et al., 2013). The ocean CO2 sink is evaluated every year as part of the Global Carbon Budget (Friedlingstein et al. 2022). The uptake of CO2 occurs primarily in response to increasing atmospheric levels. The global flux is characterized by a significant variability on interannual to decadal time scales largely in response to natural climate variability (e.g., ENSO) (Friedlingstein et al. 2022, Chau et al. 2022). '''CMEMS KEY FINDINGS''' The rate of change of the integrated yearly surface downward flux has increased by 0.04±0.03e-1 PgC/yr2 over the period 1985 to year-1. The yearly flux time series shows a plateau in the 90s followed by an increase since 2000 with a growth rate of 0.06±0.04e-1 PgC/yr2. In 2021 (resp. 2020), the global ocean CO2 sink was 2.41±0.13 (resp. 2.50±0.12) PgC/yr. The average over the full period is 1.61±0.10 PgC/yr with an interannual variability (temporal standard deviation) of 0.46 PgC/yr. In order to compare these fluxes to Friedlingstein et al. (2022), the estimate of preindustrial outgassing of riverine carbon of 0.61 PgC/yr, which is in between the estimate by Jacobson et al. (2007) (0.45±0.18 PgC/yr) and the one by Resplandy et al. (2018) (0.78±0.41 PgC/yr) needs to be added. A full discussion regarding this OMI can be found in section 2.10 of the Ocean State Report 4 (Gehlen et al., 2020) and in Chau et al. (2022). '''DOI (product):''' https://doi.org/10.48670/moi-00223

'''Short description:''' The Reprocessed (REP) Mediterranean (MED) dataset provides a stable and consistent long-term Sea Surface Temperature (SST) time series over the Mediterranean Sea (and the adjacent North Atlantic box) developed for climate applications. This product consists of daily (nighttime), merged multi-sensor (L3S), satellite-based estimates of the foundation SST (namely, the temperature free, or nearly-free, of any diurnal cycle) at 0.05° resolution grid covering the period from 1st January 1981 to present (approximately one month before real time). The MED-REP-L3S product is built from a consistent reprocessing of the collated level-3 (merged single-sensor, L3C) climate data record (CDR) v.3.0, provided by the ESA Climate Change Initiative (CCI) and covering the period up to 2021, and its interim extension (ICDR) that allows the regular temporal extension for 2022 onwards. '''DOI (product) :''' https://doi.org/10.48670/moi-00314

'''DEFINITION''' We have derived an annual eutrophication and eutrophication indicator map for the North Atlantic Ocean using satellite-derived chlorophyll concentration. Using the satellite-derived chlorophyll products distributed in the regional North Atlantic CMEMS MY Ocean Colour dataset (OC- CCI), we derived P90 and P10 daily climatologies. The time period selected for the climatology was 1998-2017. For a given pixel, P90 and P10 were defined as dynamic thresholds such as 90% of the 1998-2017 chlorophyll values for that pixel were below the P90 value, and 10% of the chlorophyll values were below the P10 value. To minimise the effect of gaps in the data in the computation of these P90 and P10 climatological values, we imposed a threshold of 25% valid data for the daily climatology. For the 20-year 1998-2017 climatology this means that, for a given pixel and day of the year, at least 5 years must contain valid data for the resulting climatological value to be considered significant. Pixels where the minimum data requirements were met were not considered in further calculations. We compared every valid daily observation over 2021 with the corresponding daily climatology on a pixel-by-pixel basis, to determine if values were above the P90 threshold, below the P10 threshold or within the [P10, P90] range. Values above the P90 threshold or below the P10 were flagged as anomalous. The number of anomalous and total valid observations were stored during this process. We then calculated the percentage of valid anomalous observations (above/below the P90/P10 thresholds) for each pixel, to create percentile anomaly maps in terms of % days per year. Finally, we derived an annual indicator map for eutrophication levels: if 25% of the valid observations for a given pixel and year were above the P90 threshold, the pixel was flagged as eutrophic. Similarly, if 25% of the observations for a given pixel were below the P10 threshold, the pixel was flagged as oligotrophic. '''CONTEXT''' Eutrophication is the process by which an excess of nutrients – mainly phosphorus and nitrogen – in a water body leads to increased growth of plant material in an aquatic body. Anthropogenic activities, such as farming, agriculture, aquaculture and industry, are the main source of nutrient input in problem areas (Jickells, 1998; Schindler, 2006; Galloway et al., 2008). Eutrophication is an issue particularly in coastal regions and areas with restricted water flow, such as lakes and rivers (Howarth and Marino, 2006; Smith, 2003). The impact of eutrophication on aquatic ecosystems is well known: nutrient availability boosts plant growth – particularly algal blooms – resulting in a decrease in water quality (Anderson et al., 2002; Howarth et al.; 2000). This can, in turn, cause death by hypoxia of aquatic organisms (Breitburg et al., 2018), ultimately driving changes in community composition (Van Meerssche et al., 2019). Eutrophication has also been linked to changes in the pH (Cai et al., 2011, Wallace et al. 2014) and depletion of inorganic carbon in the aquatic environment (Balmer and Downing, 2011). Oligotrophication is the opposite of eutrophication, where reduction in some limiting resource leads to a decrease in photosynthesis by aquatic plants, reducing the capacity of the ecosystem to sustain the higher organisms in it. Eutrophication is one of the more long-lasting water quality problems in Europe (OSPAR ICG-EUT, 2017), and is on the forefront of most European Directives on water-protection. Efforts to reduce anthropogenically-induced pollution resulted in the implementation of the Water Framework Directive (WFD) in 2000. '''CMEMS KEY FINDINGS''' The coastal and shelf waters, especially between 30 and 400N that showed active oligotrophication flags for 2020 have reduced in 2021 and a reversal to eutrophic flags can be seen in places. Again, the eutrophication index is positive only for a small number of coastal locations just north of 40oN in 2021, however south of 40oN there has been a significant increase in eutrophic flags, particularly around the Azores. In general, the 2021 indicator map showed an increase in oligotrophic areas in the Northern Atlantic and an increase in eutrophic areas in the Southern Atlantic. The Third Integrated Report on the Eutrophication Status of the OSPAR Maritime Area (OSPAR ICG-EUT, 2017) reported an improvement from 2008 to 2017 in eutrophication status across offshore and outer coastal waters of the Greater North Sea, with a decrease in the size of coastal problem areas in Denmark, France, Germany, Ireland, Norway and the United Kingdom. '''DOI (product):''' https://doi.org/10.48670/moi-00195

'''Short description:''' This product consists of 3D fields of Particulate Organic Carbon (POC), Particulate Backscattering coefficient (bbp) and Chlorophyll-a concentration (Chla) at depth. The reprocessed product is provided at 0.25°x0.25° horizontal resolution, over 36 levels from the surface to 1000 m depth. A neural network method estimates both the vertical distribution of Chla concentration and of particulate backscattering coefficient (bbp), a bio-optical proxy for POC, from merged surface ocean color satellite measurements with hydrological properties and additional relevant drivers. '''DOI (product):''' https://doi.org/10.48670/moi-00046

'''This product has been archived''' For operationnal and online products, please visit https://marine.copernicus.eu '''Short description:''' The Global Ocean Satellite monitoring and marine ecosystem study group (GOS) of the Italian National Research Council (CNR), in Rome operationally produces surface chlorophyll of the European region by merging the daily chlorophyll regional products over the Atlantic Ocean, the Baltic Sea, the Black Sea, and the Mediterranean Sea. Single chlorophyll daily images are the Case I – Case II products, which are produced accounting for bio-optical differences in these two water types. The mosaic is built using the following datasets: • dataset-oc-atl-chl-multi_cci-l3-chl_1km_daily-rt-v01 for the North Atlantic Ocean • dataset-oc-bal-chl-modis_a-l3-nn_1km_daily-rt-v01 for the Baltic Sea • dataset-oc-bs-chl-multi-l3-chl_1km_daily-rt-v02 for the Black Sea • dataset-oc-med-chl-multi-l3-chl_1km_daily-rt-v02 for the Mediterranean Sea. '''Processing information:''' All details about the processing can be found in relevant product description: *OCEANCOLOUR_ATL_CHL_L3_NRT_OBSERVATIONS_009_036 *OCEANCOLOUR_BAL_CHL_L3_NRT_OBSERVATIONS_009_049 *OCEANCOLOUR_BS_CHL_L3_NRT_OBSERVATIONS_009_044 *OCEANCOLOUR_MED_CHL_L3_NRT_OBSERVATIONS_009_040 '''Description of observation methods/instruments:''' Ocean colour technique exploits the emerging electromagnetic radiation from the sea surface in different wavelengths. The spectral variability of this signal defines the so-called ocean colour which is affected by the presence of phytoplankton. '''Quality / Accuracy / Calibration information:''' A detailed description of the calibration and validation activities performed over this product can be found on the CMEMS web portal. '''Suitability, Expected type of users / uses:''' This product is meant for use for educational purposes and for the managing of the marine safety, marine resources, marine and coastal environment and for climate and seasonal studies. '''Dataset names:''' *dataset-oc-eur-chl-multi-l3-chl_1km_daily-rt-v02 '''DOI (product) :''' https://doi.org/10.48670/moi-00095

'''DEFINITION''' The OMI_EXTREME_SST_MEDSEA_sst_mean_and_anomaly_obs indicator is based on the computation of the 99th and the 1st percentiles from in situ data (observations). It is computed for the variable sea surface temperature measured by in situ buoys at depths between 0 and 5 meters. The use of percentiles instead of annual maximum and minimum values, makes this extremes study less affected by individual data measurement errors. The percentiles are temporally averaged, and the spatial evolution is displayed, jointly with the anomaly in the target year. This study of extreme variability was first applied to sea level variable (Pérez Gómez et al 2016) and then extended to other essential variables, sea surface temperature and significant wave height (Pérez Gómez et al 2018). '''CONTEXT''' Sea surface temperature (SST) is one of the essential ocean variables affected by climate change (mean SST trends, SST spatial and interannual variability, and extreme events). In Europe, several studies show warming trends in mean SST for the last years (von Schuckmann et al., 2016; IPCC, 2021, 2022). An exception seems to be the North Atlantic, where, in contrast, anomalous cold conditions have been observed since 2014 (Mulet et al., 2018; Dubois et al. 2018; IPCC 2021, 2022). Extremes may have a stronger direct influence in population dynamics and biodiversity. According to Alexander et al. 2018 the observed warming trend will continue during the 21st Century and this can result in exceptionally large warm extremes. Monitoring the evolution of sea surface temperature extremes is, therefore, crucial. The Mediterranean Sea has showed a constant increase of the SST in the last three decades across the whole basin with more frequent and severe heat waves (Juza et al., 2022). Deep analyses of the variations have displayed a non-uniform rate in space, being the warming trend more evident in the eastern Mediterranean Sea with respect to the western side. This variation rate is also changing in time over the three decades with differences between the seasons (e.g. Pastor et al. 2018; Pisano et al. 2020), being higher in Spring and Summer, which would affect the extreme values. '''COPERNICUS MARINE SERVICE KEY FINDINGS''' The mean 99th percentiles showed in the area present values from 25ºC in Ionian Sea and 26º in the Alboran sea and Gulf of Lion to 27ºC in the East of Iberian Peninsula. The standard deviation ranges from 0.6ºC to 1.2ºC in the Western Mediterranean and is around 2.2ºC in the Ionian Sea. Results for this year show a slight negative anomaly in the Ionian Sea (-1ºC) inside the standard deviation and a clear positive anomaly in the Western Mediterranean Sea reaching +2.2ºC, almost two times the standard deviation in the area. '''DOI (product):''' https://doi.org/10.48670/moi-00267