'''This product has been archived''' For operationnal and online products, please visit https://marine.copernicus.eu '''Short description:''' The Global Ocean Satellite monitoring and marine ecosystem study group (GOS) of the Italian National Research Council (CNR), in Rome, distributes Level-4 product including the daily interpolated chlorophyll field with no data voids starting from the multi-sensor (MODIS-Aqua, NOAA-20-VIIRS, NPP-VIIRS, Sentinel3A-OLCI at 300m of resolution) (at 1 km resolution) and the monthly averaged chlorophyll concentration for the multi-sensor (at 1 km resolution) and Sentinel-OLCI Level-3 (at 300m resolution). Chlorophyll field are obtained by means of the Mediterranean regional algorithms: an updated version of the MedOC4 (Case 1 waters, Volpe et al., 2019, with new coefficients) and AD4 (Case 2 waters, Berthon and Zibordi, 2004). Discrimination between the two water types is performed by comparing the satellite spectrum with the average water type spectral signature from in situ measurements for both water types. Reference insitu dataset is MedBiOp (Volpe et al., 2019) where pure Case II spectra are selected using a k-mean cluster analysis (Melin et al., 2015). Merging of Case I and Case II information is performed estimating the Mahalanobis distance between the observed and reference spectra and using it as weight for the final merged value. The interpolated gap-free Level-4 Chl concentration is estimated by means of a modified version of the DINEOF algorithm by GOS (Volpe et al., 2018). DINEOF is an iterative procedure in which EOF are used to reconstruct the entire field domain. As first guess, it uses the SeaWiFS-derived daily climatological values at missing pixels and satellite observations at valid pixels. The other Level-4 dataset is the time averages of the L3 fields and includes the standard deviation and the number of observations in the monthly period of integration. '''Processing information:''' Multi-sensor products are constituted by MODIS-AQUA, NOAA20-VIIRS, NPP-VIIRS and Sentinel3A-OLCI. For consistency with NASA L2 dataset, BRDF correction was applied to Sentinel3A-OLCI prior to band shifting and multi sensor merging. Hence, the single sensor OLCI data set is also distributed after BRDF correction. Single sensor NASA Level-2 data are destriped and then all Level-2 data are remapped at 1 km spatial resolution (300m for Sentinel3A-OLCI) using cylindrical equirectangular projection. Afterwards, single sensor Rrs fields are band-shifted, over the SeaWiFS native bands (using the QAAv6 model, Lee et al., 2002) and merged with a technique aimed at smoothing the differences among different sensors. This technique is developed by The Global Ocean Satellite monitoring and marine ecosystem study group (GOS) of the Italian National Research Council (CNR, Rome). Then geophysical fields (i.e. chlorophyll, kd490, bbp, aph and adg) are estimated via state-of-the-art algorithms for better product quality. Level-4 includes both monthly time averages and the daily-interpolated fields. Time averages are computed on the delayed-time data. The interpolated product starts from the L3 products at 1 km resolution. At the first iteration, DINEOF procedure uses, as first guess for each of the missing pixels the relative daily climatological pixel. A procedure to smooth out spurious spatial gradients is applied to the daily merged image (observation and climatology). From the second iteration, the procedure uses, as input for the next one, the field obtained by the EOF calculation, using only a number of modes: that is, at the second round, only the first two modes, at the third only the first three, and so on. At each iteration, the same smoothing procedure is applied between EOF output and initial observations. The procedure stops when the variance explained by the current EOF mode exceeds that of noise. '''Description of observation methods/instruments:''' Ocean colour technique exploits the emerging electromagnetic radiation from the sea surface in different wavelengths. The spectral variability of this signal defines the so-called ocean colour which is affected by the pre+D2sence of phytoplankton. '''Quality / Accuracy / Calibration information:''' A detailed description of the calibration and validation activities performed over this product can be found on the CMEMS web portal. '''Suitability, Expected type of users / uses:''' This product is meant for use for educational purposes and for the managing of the marine safety, marine resources, marine and coastal environment and for climate and seasonal studies. '''Dataset names:''' *dataset-oc-med-chl-multi-l4-chl_1km_monthly-rt-v02 *dataset-oc-med-chl-multi-l4-interp_1km_daily-rt-v02 *dataset-oc-med-chl-olci-l4-chl_300m_monthly-rt-v02 '''Files format:''' *CF-1.4 *INSPIRE compliant '''DOI (product) :''' https://doi.org/10.48670/moi-00113

'''This product has been archived''' For operationnal and online products, please visit https://marine.copernicus.eu '''Short description:''' The Global Ocean Satellite monitoring and marine ecosystem study group (GOS) of the Italian National Research Council (CNR), in Rome operationally produces surface chlorophyll of the European region by merging the daily chlorophyll regional products over the Atlantic Ocean, the Baltic Sea, the Black Sea, and the Mediterranean Sea. Single chlorophyll daily images are the Case I – Case II products, which are produced accounting for bio-optical differences in these two water types. The mosaic is built using the following datasets: • dataset-oc-atl-chl-multi_cci-l3-chl_1km_daily-rt-v01 for the North Atlantic Ocean • dataset-oc-bal-chl-modis_a-l3-nn_1km_daily-rt-v01 for the Baltic Sea • dataset-oc-bs-chl-multi-l3-chl_1km_daily-rt-v02 for the Black Sea • dataset-oc-med-chl-multi-l3-chl_1km_daily-rt-v02 for the Mediterranean Sea. '''Processing information:''' All details about the processing can be found in relevant product description: *OCEANCOLOUR_ATL_CHL_L3_NRT_OBSERVATIONS_009_036 *OCEANCOLOUR_BAL_CHL_L3_NRT_OBSERVATIONS_009_049 *OCEANCOLOUR_BS_CHL_L3_NRT_OBSERVATIONS_009_044 *OCEANCOLOUR_MED_CHL_L3_NRT_OBSERVATIONS_009_040 '''Description of observation methods/instruments:''' Ocean colour technique exploits the emerging electromagnetic radiation from the sea surface in different wavelengths. The spectral variability of this signal defines the so-called ocean colour which is affected by the presence of phytoplankton. '''Quality / Accuracy / Calibration information:''' A detailed description of the calibration and validation activities performed over this product can be found on the CMEMS web portal. '''Suitability, Expected type of users / uses:''' This product is meant for use for educational purposes and for the managing of the marine safety, marine resources, marine and coastal environment and for climate and seasonal studies. '''Dataset names:''' *dataset-oc-eur-chl-multi-l3-chl_1km_daily-rt-v02 '''DOI (product) :''' https://doi.org/10.48670/moi-00095

'''This product has been archived''' '''DEFINITION''' Estimates of Ocean Heat Content (OHC) are obtained from integrated differences of the measured temperature and a climatology along a vertical profile in the ocean (von Schuckmann et al., 2018). The regional OHC values are then averaged from 60°S-60°N aiming i) to obtain the mean OHC as expressed in Joules per meter square (J/m2) to monitor the large-scale variability and change. ii) to monitor the amount of energy in the form of heat stored in the ocean (i.e. the change of OHC in time), expressed in Watt per square meter (W/m2). Ocean heat content is one of the six Global Climate Indicators recommended by the World Meterological Organisation for Sustainable Development Goal 13 implementation (WMO, 2017). '''CONTEXT''' Knowing how much and where heat energy is stored and released in the ocean is essential for understanding the contemporary Earth system state, variability and change, as the ocean shapes our perspectives for the future (von Schuckmann et al., 2020). Variations in OHC can induce changes in ocean stratification, currents, sea ice and ice shelfs (IPCC, 2019; 2021); they set time scales and dominate Earth system adjustments to climate variability and change (Hansen et al., 2011); they are a key player in ocean-atmosphere interactions and sea level change (WCRP, 2018) and they can impact marine ecosystems and human livelihoods (IPCC, 2019). '''CMEMS KEY FINDINGS''' Regional trends for the period 2005-2019 from the Copernicus Marine Service multi-ensemble approach show warming at rates ranging from the global mean average up to more than 8 W/m2 in some specific regions (e.g. northern hemisphere western boundary current regimes). There are specific regions where a negative trend is observed above noise at rates up to about -5 W/m2 such as in the subpolar North Atlantic, or the western tropical Pacific. These areas are characterized by strong year-to-year variability (Dubois et al., 2018; Capotondi et al., 2020). Note: The key findings will be updated annually in November, in line with OMI evolutions. '''DOI (product):''' https://doi.org/10.48670/moi-00236

'''This product has been archived''' This dataset provide a times series of gap free map of Sea Surface Temperature (SST) foundation at high resolution on a 0.10 x 0.10 degree grid (approximately 10 x 10 km) for the Global Ocean, every 24 hours. Whereas along swath observation data essentially represent the skin or sub-skin SST, the Level 4 SST product is defined to represent the SST foundation (SSTfnd). SSTfnd is defined within GHRSST as the temperature at the base of the diurnal thermocline. It is so named because it represents the foundation temperature on which the diurnal thermocline develops during the day. SSTfnd changes only gradually along with the upper layer of the ocean, and by definition it is independent of skin SST fluctuations due to wind- and radiation-dependent diurnal stratification or skin layer response. It is therefore updated at intervals of 24 hrs. SSTfnd corresponds to the temperature of the upper mixed layer which is the part of the ocean represented by the top-most layer of grid cells in most numerical ocean models. It is never observed directly by satellites, but it comes closest to being detected by infrared and microwave radiometers during the night, when the previous day's diurnal stratification can be assumed to have decayed. The processing combines the observations of multiple polar orbiting and geostationary satellites, embedding infrared of microwave radiometers. All these sources are intercalibrated with each other before merging. A ranking procedure is used to select the best sensor observation for each grid point. An optimal interpolation is used to fill in where observations are missing. '''DOI (product) :''' https://doi.org/10.48670/mds-00321

'''This product has been archived''' For operationnal and online products, please visit https://marine.copernicus.eu '''Short description :''' For the '''Global''' Ocean '''Satellite Observations''', ACRI-ST company (Sophia Antipolis, France) is providing '''Chlorophyll-a''' and '''Optics''' products [1997 - present] based on the '''Copernicus-GlobColour''' processor. * '''Chlorophyll and Bio''' products refer to Chlorophyll-a, Primary Production (PP) and Phytoplankton Functional types (PFT). Products are based on a multi sensors/algorithms approach to provide to end-users the best estimate. Two dailies Chlorophyll-a products are distributed: ** one limited to the daily observations (called L3), ** the other based on a space-time interpolation: the '''Cloud Free''' (called L4). * '''Optics''' products refer to Reflectance (RRS), Suspended Matter (SPM), Particulate Backscattering (BBP), Secchi Transparency Depth (ZSD), Diffuse Attenuation (KD490) and Absorption Coef. (ADG/CDM). * The spatial resolution is 4 km. For Chlorophyll, a 1 km over the Atlantic (46°W-13°E , 20°N-66°N) is also available for the '''Cloud Free''' product, plus a 300m Global coastal product (OLCI S3A & S3B merged). *Products (Daily, Monthly and Climatology) are based on the merging of the sensors SeaWiFS, MODIS, MERIS, VIIRS-SNPP&JPSS1, OLCI-S3A&S3B. Additional products using only OLCI upstreams are also delivered. * Recent products are organized in datasets called NRT (Near Real Time) and long time-series in datasets called REP/MY (Multi-Years). The NRT products are provided one day after satellite acquisition and updated a few days after in Delayed Time (DT) to provide a better quality. An uncertainty is given at pixel level for all products. To find the '''Copernicus-GlobColour''' products in the catalogue, use the search keyword '''GlobColour'''. See [http://catalogue.marine.copernicus.eu/documents/QUID/CMEMS-OC-QUID-009-030-032-033-037-081-082-083-085-086-098.pdf QUID document] for a detailed description and assessment. '''DOI (product) :''' https://doi.org/10.48670/moi-00096

'''This product has been archived''' '''DEFINITION''' The temporal evolution of thermosteric sea level in an ocean layer is obtained from an integration of temperature driven ocean density variations, which are subtracted from a reference climatology to obtain the fluctuations from an average field. The regional thermosteric sea level values are then averaged from 60°S-60°N aiming to monitor interannual to long term global sea level variations caused by temperature driven ocean volume changes through thermal expansion as expressed in meters (m). '''CONTEXT''' The global mean sea level is reflecting changes in the Earth’s climate system in response to natural and anthropogenic forcing factors such as ocean warming, land ice mass loss and changes in water storage in continental river basins. Thermosteric sea-level variations result from temperature related density changes in sea water associated with volume expansion and contraction. Global thermosteric sea level rise caused by ocean warming is known as one of the major drivers of contemporary global mean sea level rise (Cazenave et al., 2018; Oppenheimer et al., 2019). '''CMEMS KEY FINDINGS''' Since the year 2005 the upper (0-2000m) near-global (60°S-60°N) thermosteric sea level rises at a rate of 1.3±0.2 mm/year. Note: The key findings will be updated annually in November, in line with OMI evolutions. '''DOI (product):''' https://doi.org/10.48670/moi-00240

'''Short description:''' Global Ocean- in-situ Near Real time Carbon observations. The In Situ Thematic Assembly Centre (INS TAC) integrates near real-time in situ observation data. This Near-Real Time product contains observations of temperature, salinity and fugacity of carbon dioxide from the surface ocean. These data are collected from ICOS Ocean Thematic Centre (https://otc.icos-cp.eu/home) operational stations, using Standard Operating Procedures for the ocean carbon community. The data are quality controlled using the software QuinCe, which provides automatic Quality Control in the form of range checks, constant value and excessive gradient detection. This product is updated with new observations at a maximum frequency of once a day, depending on the connection capabilities of the platform.

'''DEFINITION''' We have derived an annual eutrophication and eutrophication indicator map for the North Atlantic Ocean using satellite-derived chlorophyll concentration. Using the satellite-derived chlorophyll products distributed in the regional North Atlantic CMEMS MY Ocean Colour dataset (OC- CCI), we derived P90 and P10 daily climatologies. The time period selected for the climatology was 1998-2017. For a given pixel, P90 and P10 were defined as dynamic thresholds such as 90% of the 1998-2017 chlorophyll values for that pixel were below the P90 value, and 10% of the chlorophyll values were below the P10 value. To minimise the effect of gaps in the data in the computation of these P90 and P10 climatological values, we imposed a threshold of 25% valid data for the daily climatology. For the 20-year 1998-2017 climatology this means that, for a given pixel and day of the year, at least 5 years must contain valid data for the resulting climatological value to be considered significant. Pixels where the minimum data requirements were met were not considered in further calculations. We compared every valid daily observation over 2021 with the corresponding daily climatology on a pixel-by-pixel basis, to determine if values were above the P90 threshold, below the P10 threshold or within the [P10, P90] range. Values above the P90 threshold or below the P10 were flagged as anomalous. The number of anomalous and total valid observations were stored during this process. We then calculated the percentage of valid anomalous observations (above/below the P90/P10 thresholds) for each pixel, to create percentile anomaly maps in terms of % days per year. Finally, we derived an annual indicator map for eutrophication levels: if 25% of the valid observations for a given pixel and year were above the P90 threshold, the pixel was flagged as eutrophic. Similarly, if 25% of the observations for a given pixel were below the P10 threshold, the pixel was flagged as oligotrophic. '''CONTEXT''' Eutrophication is the process by which an excess of nutrients – mainly phosphorus and nitrogen – in a water body leads to increased growth of plant material in an aquatic body. Anthropogenic activities, such as farming, agriculture, aquaculture and industry, are the main source of nutrient input in problem areas (Jickells, 1998; Schindler, 2006; Galloway et al., 2008). Eutrophication is an issue particularly in coastal regions and areas with restricted water flow, such as lakes and rivers (Howarth and Marino, 2006; Smith, 2003). The impact of eutrophication on aquatic ecosystems is well known: nutrient availability boosts plant growth – particularly algal blooms – resulting in a decrease in water quality (Anderson et al., 2002; Howarth et al.; 2000). This can, in turn, cause death by hypoxia of aquatic organisms (Breitburg et al., 2018), ultimately driving changes in community composition (Van Meerssche et al., 2019). Eutrophication has also been linked to changes in the pH (Cai et al., 2011, Wallace et al. 2014) and depletion of inorganic carbon in the aquatic environment (Balmer and Downing, 2011). Oligotrophication is the opposite of eutrophication, where reduction in some limiting resource leads to a decrease in photosynthesis by aquatic plants, reducing the capacity of the ecosystem to sustain the higher organisms in it. Eutrophication is one of the more long-lasting water quality problems in Europe (OSPAR ICG-EUT, 2017), and is on the forefront of most European Directives on water-protection. Efforts to reduce anthropogenically-induced pollution resulted in the implementation of the Water Framework Directive (WFD) in 2000. '''CMEMS KEY FINDINGS''' The coastal and shelf waters, especially between 30 and 400N that showed active oligotrophication flags for 2020 have reduced in 2021 and a reversal to eutrophic flags can be seen in places. Again, the eutrophication index is positive only for a small number of coastal locations just north of 40oN in 2021, however south of 40oN there has been a significant increase in eutrophic flags, particularly around the Azores. In general, the 2021 indicator map showed an increase in oligotrophic areas in the Northern Atlantic and an increase in eutrophic areas in the Southern Atlantic. The Third Integrated Report on the Eutrophication Status of the OSPAR Maritime Area (OSPAR ICG-EUT, 2017) reported an improvement from 2008 to 2017 in eutrophication status across offshore and outer coastal waters of the Greater North Sea, with a decrease in the size of coastal problem areas in Denmark, France, Germany, Ireland, Norway and the United Kingdom. '''DOI (product):''' https://doi.org/10.48670/moi-00195

'''Short description:''' For the Baltic Sea- The DMI Sea Surface Temperature reprocessed analysis provides daily gap-free sea surface temperature fields, referred as L4 product, at 0.02deg. x 0.02deg. horizontal resolution. It is produced by the DMI Optimal Interpolation (DMIOI) system (Høyer and She, 2007) to provide a high resolution (1/50deg. - approx. 2km grid resolution) daily analysis of the daily average sea surface temperature (SST) at 20 cm depth. It uses satellite data from infra-red radiometers, from the ESA SST_cci v3.0 (Embury et al., 2024) and Copernicus C3S projects, namely L2P data from (A)ATSRs, SLSTR and AVHRR for the period 1982-2021, L3U data from SLSTR and AVHRR for 2022-July 19 2024 and L2P data from SLSTR and AVHRR from July 20 2024 onward. For the Sea Ice Concentration it uses the Baltic high resolution sea ice concentration data from the Copernicus Marine Service SI TAC (SEAICE_BAL_PHY_L4_MY_011_019). '''DOI (product) :''' https://doi.org/10.48670/moi-00156

'''DEFINITION''' The regional annual chlorophyll anomaly is computed by subtracting a reference climatology (1997-2014) from the annual chlorophyll mean, on a pixel-by-pixel basis and in log10 space. Both the annual mean and the climatology are computed employing the regional products as distributed by CMEMS, derived by application of the regional chlorophyll algorithms over remote sensing reflectances (Rrs) produced by the Plymouth Marine Laboratory (PML) using the ESA Ocean Colour Climate Change Initiative processor (ESA OC-CCI, Sathyendranath et al., 2018a). '''CONTEXT''' Phytoplankton and chlorophyll concentration as their proxy respond rapidly to changes in their physical environment. In the Mediterranean Sea, these changes are seasonal and are mostly determined by light and nutrient availability (Gregg and Rousseaux, 2014). By comparing annual mean values to the climatology, we effectively remove the seasonal signal at each grid point, while retaining information on peculiar events during the year. In particular, chlorophyll anomalies in the Mediterranean Sea can then be correlated with the North Atlantic Oscillation (NAO) and El Niño Southern Oscillation (ENSO) (Basterretxea et al 2018, Colella et al 2016). '''CMEMS KEY FINDINGS''' The 2019 average chlorophyll anomaly in the Mediterranean Sea is 1.02 mg m-3 (0.005 in log10 [mg m-3]), with a maximum value of 73 mg m-3 (1.86 log10 [mg m-3]) and a minimum value of 0.04 mg m-3 (-1.42 log10 [mg m-3]). The overall east west divided pattern reported in 2016, showing negative anomalies for the Western Mediterranean Sea and positive anomalies for the Levantine Sea (Sathyendranath et al., 2018b) is modified in 2019, with a widespread positive anomaly all over the eastern basin, which reaches the western one, up to the offshore water at the west of Sardinia. Negative anomaly values occur in the coastal areas of the basin and in some sectors of the Alboràn Sea. In the northwestern Mediterranean the values switch to be positive again in contrast to the negative values registered in 2017 anomaly. The North Adriatic Sea shows a negative anomaly offshore the Po river, but with weaker value with respect to the 2017 anomaly map.