'''This product has been archived''' For operationnal and online products, please visit https://marine.copernicus.eu '''Short description:''' For the Global ocean, the ESA Ocean Colour CCI surface Chlorophyll (mg m-3, 4 km resolution) using the OC-CCI recommended chlorophyll algorithm is made available in CMEMS format. L3 products are daily files, while the L4 are monthly composites. ESA-CCI data are provided by Plymouth Marine Laboratory at 4km resolution. These are processed using the same in-house software as in the operational processing. Standard masking criteria for detecting clouds or other contamination factors have been applied during the generation of the Rrs, i.e., land, cloud, sun glint, atmospheric correction failure, high total radiance, large solar zenith angle (actually a high air mass cutoff, but approximating to 70deg zenith), coccolithophores, negative water leaving radiance, and normalized water leaving radiance at 555 nm 0.15 Wm-2 sr-1 (McClain et al., 1995). Ocean colour technique exploits the emerging electromagnetic radiation from the sea surface in different wavelengths. The spectral variability of this signal defines the so called ocean colour which is affected by the presence of phytoplankton. By comparing reflectances at different wavelengths and calibrating the result against in-situ measurements, an estimate of chlorophyll content can be derived. A detailed description of calibration & validation is given in the relevant QUID, associated validation reports and quality documentation. '''Processing information:''' ESA-CCI data are provided by Plymouth Marine Laboratory at 4km resolution. These are processed using the same in-house software as in the operational processing. The entire CCI data set is consistent and processing is done in one go. Both OC CCI and the REP product are versioned. Standard masking criteria for detecting clouds or other contamination factors have been applied during the generation of the Rrs, i.e., land, cloud, sun glint, atmospheric correction failure, high total radiance, large solar zenith angle (actually a high air mass cutoff, but approximating to 70deg zenith), coccolithophores, negative water leaving radiance, and normalized water leaving radiance at 555 nm 0.15 Wm-2 sr-1 (McClain et al., 1995). '''Description of observation methods/instruments:''' Ocean colour technique exploits the emerging electromagnetic radiation from the sea surface in different wavelengths. The spectral variability of this signal defines the so called ocean colour which is affected by the presence of phytoplankton. By comparing reflectances at different wavelengths and calibrating the result against in-situ measurements, an estimate of chlorophyll content can be derived. '''Quality / Accuracy / Calibration information:''' Detailed description of cal/val is given in the relevant QUID, associated validation reports and quality documentation. '''Suitability, Expected type of users / uses:''' This product is meant for use for educational purposes and for the managing of the marine safety, marine resources, marine and coastal environment and for climate and seasonal studies. '''DOI (product) :''' https://doi.org/10.48670/moi-00101

'''DEFINITION''' The Mediterranean water mass formation rates are evaluated in 4 areas as defined in the Ocean State Report issue 2 (OSR2, von Schuckmann et al., 2018) section 3.4 (Simoncelli and Pinardi, 2018): (1) the Gulf of Lions for the Western Mediterranean Deep Waters (WMDW); (2) the Southern Adriatic Sea Pit for the Eastern Mediterranean Deep Waters (EMDW); (3) the Cretan Sea for Cretan Intermediate Waters (CIW) and Cretan Deep Waters (CDW); (4) the Rhodes Gyre, the area of formation of the so-called Levantine Intermediate Waters (LIW) and Levantine Deep Waters (LDW). Annual water mass formation rates have been computed using daily mixed layer depth estimates (density criteria Δσ = 0.01 kg/m3, 10 m reference level) considering the annual maximum volume of water above mixed layer depth with potential density within or higher the specific thresholds specified in Table 1 then divided by seconds per year. Annual mean values are provided using the Mediterranean 1/24o eddy resolving reanalysis (Escudier et al. 2020, 2021). Time spans from 1987 to the year preceding the current one [-1Y], operationally extended yearly. '''CONTEXT''' The formation of intermediate and deep water masses is one of the most important processes occurring in the Mediterranean Sea, being a component of its general overturning circulation. This circulation varies at interannual and multidecadal time scales and it is composed of an upper zonal cell (Zonal Overturning Circulation) and two main meridional cells in the western and eastern Mediterranean (Pinardi and Masetti 2000). The objective is to monitor the main water mass formation events using the eddy resolving Mediterranean Sea Reanalysis (MEDSEA_MULTIYEAR_PHY_006_004, Escudier et al. 2020, 2021) and considering Pinardi et al. (2015) and Simoncelli and Pinardi (2018) as references for the methodology. The Mediterranean Sea Reanalysis can reproduce both Eastern Mediterranean Transient and Western Mediterranean Transition phenomena and catches the principal water mass formation events reported in the literature. This will permit constant monitoring of the open ocean deep convection process in the Mediterranean Sea and a better understanding of the multiple drivers of the general overturning circulation at interannual and multidecadal time scales. Deep and intermediate water formation events reveal themselves by a deep mixed layer depth distribution in four Mediterranean areas: Gulf of Lions, Southern Adriatic Sea Pit, Cretan Sea and Rhodes Gyre. '''KEY FINDINGS''' The Western Mediterranean Deep Water (WMDW) formation events in the Gulf of Lion appear to be larger after 1999 consistently with Schroeder et al. (2006, 2008) related to the Eastern Mediterranean Transient event. This modification of WMDW after 2005 has been called Western Mediterranean Transition. WMDW formation events are consistent with Somot et al. (2016) and the event in 2009 is also reported in Houpert et al. (2016). The Eastern Mediterranean Deep Water (EMDW) formation in the Southern Adriatic Pit region displays a period of water mass formation between 1988 and 1993, in agreement with Pinardi et al. (2015), in 1996, 1999 and 2000 as documented by Manca et al. (2002). Weak deep water formation in winter 2006 is confirmed by observations in Vilibić and Šantić (2008). An intense deep water formation event is detected in 2012-2013 (Gačić et al., 2014). Last years are characterized by large events starting from 2017 (Mihanovic et al., 2021). Cretan Intermediate Water formation rates present larger peaks between 1989 and 1993 with the ones in 1992 and 1993 composing the Eastern Mediterranean Transient phenomena. The Cretan Deep Water formed in 1992 and 1993 is characterized by the highest densities of the entire period in accordance with Velaoras et al. (2014). The Levantine Deep Water formation rate in the Rhode Gyre region presents the largest values between 1992 and 1993 in agreement with Kontoyiannis et al. (1999). '''DOI (product):''' https://doi.org/10.48670/mds-00318

'''This product has been archived''' For operationnal and online products, please visit https://marine.copernicus.eu '''Short description:''' For the Global Ocean- In-situ observation yearly delivery in delayed mode. The In Situ delayed mode product designed for reanalysis purposes integrates the best available version of in situ data for temperature and salinity measurements. These data are collected from main global networks (Argo, GOSUD, OceanSITES, World Ocean Database) completed by European data provided by EUROGOOS regional systems and national system by the regional INS TAC components. It is updated on a yearly basis. This version is a merged product between the previous verion of CORA and EN4 distributed by the Met Office for the period 1950-1990. '''DOI (product) :''' https://doi.org/10.17882/46219

'''This product has been archived''' "''DEFINITION''' Marine primary production corresponds to the amount of inorganic carbon which is converted into organic matter during the photosynthesis, and which feeds upper trophic layers. The daily primary production is estimated from satellite observations with the Antoine and Morel algorithm (1996). This algorithm modelized the potential growth in function of the light and temperature conditions, and with the chlorophyll concentration as a biomass index. The monthly area average is computed from monthly primary production weighted by the pixels size. The trend is computed from the deseasonalised time series (1998-2022), following the Vantrepotte and Mélin (2009) method. The trend estimate is not shown because the length of the time series does not allow to completely differentiate the climate trend to the natural variability of the primary production. More details are provided in the Ocean State Reports 4 (Cossarini et al. ,2020). '''CONTEXT''' Marine primary production is at the basis of the marine food web and produce about 50% of the oxygen we breath every year (Behrenfeld et al., 2001). Study primary production is of paramount importance as ocean health and fisheries are directly linked to the primary production (Pauly and Christensen, 1995, Fee et al., 2019). Changes in primary production can have consequences on biogeochemical cycles, and specially on the carbon cycle, and impact the biological carbon pump intensity, and therefore climate (Chavez et al., 2011). Despite its importance for climate and socio-economics resources, primary production measurements are scarce and do not allow a deep investigation of the primary production evolution over decades. Satellites observations and modelling can fill this gap. However, depending of their parametrisation, models can predict an increase or a decrease in primary production by the end of the century (Laufkötter et al., 2015). Primary production from satellite observations presents therefore the advantage to dispose an archive of more than two decades of global data. This archive can be assimilated in models, in addition to direct environmental analysis, to minimise models uncertainties (Gregg and Rousseaux, 2019). In the Ocean State Reports 4, primary production estimate from satellite and from modelling are compared at the scale of the Mediterranean Sea. This demonstrates the ability of such a comparison to deeply investigate physical and biogeochemical processes associated to the primary production evolution (Cossarini et al., 2020) '''CMEMS KEY FINDINGS''' Global primary production does not show specific trend and remain relatively constant over the archive 1998-2022. The temporal variability of the primary production appears to be mainly driven by the seasonal variation. However, some specific inter-annual event may induce noticeable increase or decrease in primary production, as for example in the second part of 2011. '''DOI (product):''' https://doi.org/10.48670/moi-00225

'''This product has been archived''' For operationnal and online products, please visit https://marine.copernicus.eu '''Short description:''' Global Ocean- Gridded objective analysis fields of temperature and salinity using profiles from the reprocessed in-situ global product CORA (INSITU_GLO_TS_REP_OBSERVATIONS_013_001_b) using the ISAS software. Objective analysis is based on a statistical estimation method that allows presenting a synthesis and a validation of the dataset, providing a validation source for operational models, observing seasonal cycle and inter-annual variability. '''DOI (product) :''' https://doi.org/10.48670/moi-00038

'''This product has been archived''' For operationnal and online products, please visit https://marine.copernicus.eu '''Short description:''' For the Global Ocean- Gridded objective analysis fields of temperature and salinity using profiles from the in-situ near real time database are produced monthly. Objective analysis is based on a statistical estimation method that allows presenting a synthesis and a validation of the dataset, providing a support for localized experience (cruises), providing a validation source for operational models, observing seasonal cycle and inter-annual variability. '''DOI (product) :''' https://doi.org/10.48670/moi-00037

'''This product has been archived'''                For operationnal and online products, please visit https://marine.copernicus.eu '''DEFINITION''' The BALTIC_OMI_TEMPSAL_sst_area_averaged_anomalies product includes time series of monthly mean SST anomalies over the period 1993-2021, relative to the 1993-2014 climatology, averaged for the Baltic Sea. The OMI time series runs from Jan 1, 1993 to December 31, 2021 and is constructed by calculating monthly averages from the daily level 4 SST analysis fields of the SST_BAL_SST_L4_REP_OBSERVATIONS_010_016 product from 1993 to 2021. See the Copernicus Marine Service Ocean State Reports (section 1.1 in Von Schuckmann et al., 2016; section 3 in Von Schuckmann et al., 2018) for more information on the OMI product. '''CONTEXT''' Sea Surface Temperature (SST) is an Essential Climate Variable (GCOS), that is an important input for initialis-ing numerical weather prediction models and fundamental for understanding air-sea interactions and moni-toring climate change (GCOS 2010). The Baltic Sea is a region that requires special attention regarding the use of satellite SST records and the assessment of climatic variability (Høyer and She 2007; Høyer and Karagali 2016). The Baltic Sea is a semi-enclosed basin affected bynatural variability, influenced by large-scale atmos-pheric processes and by the vicinity of land. In addition, the Baltic Sea is one of the largest brackish seas in the world. When analysing regional-scale climate variability, all these effects have to be considered, which re-quires dedicated regional and validated SST products. Satellite observations have previously been used to ana-lyse the climatic SST signals in the North Sea and Baltic Sea (BACC II Author Team 2015; Lehmann et al. 2011). Recently, Høyer and Karagali (2016) demonstrated that the Baltic Sea had warmed 1-2 oC from 1982 to 2012 considering all months of the year and 3-5 oC when only July-September months were considered. This was corroborated in the Ocean State Reports (section 1.1 in Von Schuckmann et al., 2016 and section 3 in Von Schuckmann et al., 2018). '''CMEMS KEY FINDINGS''' The basin-average trend of SST anomalies for Baltic Sea region amounts to 0.049±0.006 °C/year over the pe-riod 1993-2021 which corresponds to an average warming of 1.42°C. Adding the North Sea area, the average trend amounts to 0.03±0.003 °C/year over the same period, which corresponds to an average warming of 0.87°C for the entire region since 1993. '''DOI (product):''' https://doi.org/10.48670/moi-00205

'''This product has been archived''' For operationnal and online products, please visit https://marine.copernicus.eu '''Short description:''' For the European Ocean - Sea Surface Temperature Mono-Sensor L3 Observations. One SST file per 24h per area and per sensor (bias corrected) closest to the original resolution: SLSTR-A, AMSR2, SEVIRI, AVHRR_METOP_B, AVHRR18_G, AVHRR_19L, MODIS_A, MODIS_T, VIIRS_NPP. One SST file per file window per area and per sensor (bias corrected) closest to the original resolution , while still manageable in terms volume over the processed area. '''Description of observation methods/instruments:''' The METOP_B derived SSTs are not bias corrected because METOP_B is used as the reference sensor for the correction method. '''DOI (product) :''' https://doi.org/10.48670/moi-00162

'''This product has been archived''' For operationnal and online products, please visit https://marine.copernicus.eu '''Short description:''' For the Global Ocean- In-situ observation delivered in delayed mode. This In Situ delayed mode product integrates the best available version of in situ oxygen, chlorophyll / fluorescence and nutrients data '''DOI (product) :''' https://doi.org/10.17882/86207

'''DEFINITION''' Ocean heat content (OHC) is defined here as the deviation from a reference period (1993-2014) and is closely proportional to the average temperature change from z1 = 0 m to z2 = 700 m depth: OHC=∫_(z_1)^(z_2)ρ_0 c_p (T_yr-T_clim )dz [1] with a reference density of = 1030 kgm-3 and a specific heat capacity of cp = 3980 J kg-1 °C-1 (e.g. von Schuckmann et al., 2009). Time series of annual mean values area averaged ocean heat content is provided for the Mediterranean Sea (30°N, 46°N; 6°W, 36°E) and is evaluated for topography deeper than 300m. '''CONTEXT''' Knowing how much and where heat energy is stored and released in the ocean is essential for understanding the contemporary Earth system state, variability and change, as the oceans shape our perspectives for the future. The quality evaluation of MEDSEA_OMI_OHC_area_averaged_anomalies is based on the “multi-product” approach as introduced in the second issue of the Ocean State Report (von Schuckmann et al., 2018), and following the MyOcean’s experience (Masina et al., 2017). Six global products and a regional (Mediterranean Sea) product have been used to build an ensemble mean, and its associated ensemble spread. The reference products are: • The Mediterranean Sea Reanalysis at 1/24 degree horizontal resolution (MEDSEA_MULTIYEAR_PHY_006_004, DOI: https://doi.org/10.25423/CMCC/MEDSEA_MULTIYEAR_PHY_006_004_E3R1, Escudier et al., 2020) • Four global reanalyses at 1/4 degree horizontal resolution (GLOBAL_MULTIYEAR_PHY_ENS_001_031): GLORYS, C-GLORS, ORAS5, FOAM • Two observation based products: CORA (INSITU_GLO_PHY_TS_OA_MY_013_052) and ARMOR3D (MULTIOBS_GLO_PHY_TSUV_3D_MYNRT_015_012). Details on the products are delivered in the PUM and QUID of this OMI. '''CMEMS KEY FINDINGS''' The ensemble mean ocean heat content anomaly time series over the Mediterranean Sea shows a continuous increase in the period 1993-2022 at rate of 1.38±0.08 W/m2 in the upper 700m. After 2005 the rate has clearly increased with respect the previous decade, in agreement with Iona et al. (2018). '''DOI (product):''' https://doi.org/10.48670/moi-00261