'''This product has been archived''' For operationnal and online products, please visit https://marine.copernicus.eu '''Short description:''' For the Global ocean, the ESA Ocean Colour CCI surface Chlorophyll (mg m-3, 4 km resolution) using the OC-CCI recommended chlorophyll algorithm is made available in CMEMS format. L3 products are daily files, while the L4 are monthly composites. ESA-CCI data are provided by Plymouth Marine Laboratory at 4km resolution. These are processed using the same in-house software as in the operational processing. Standard masking criteria for detecting clouds or other contamination factors have been applied during the generation of the Rrs, i.e., land, cloud, sun glint, atmospheric correction failure, high total radiance, large solar zenith angle (actually a high air mass cutoff, but approximating to 70deg zenith), coccolithophores, negative water leaving radiance, and normalized water leaving radiance at 555 nm 0.15 Wm-2 sr-1 (McClain et al., 1995). Ocean colour technique exploits the emerging electromagnetic radiation from the sea surface in different wavelengths. The spectral variability of this signal defines the so called ocean colour which is affected by the presence of phytoplankton. By comparing reflectances at different wavelengths and calibrating the result against in-situ measurements, an estimate of chlorophyll content can be derived. A detailed description of calibration & validation is given in the relevant QUID, associated validation reports and quality documentation. '''Processing information:''' ESA-CCI data are provided by Plymouth Marine Laboratory at 4km resolution. These are processed using the same in-house software as in the operational processing. The entire CCI data set is consistent and processing is done in one go. Both OC CCI and the REP product are versioned. Standard masking criteria for detecting clouds or other contamination factors have been applied during the generation of the Rrs, i.e., land, cloud, sun glint, atmospheric correction failure, high total radiance, large solar zenith angle (actually a high air mass cutoff, but approximating to 70deg zenith), coccolithophores, negative water leaving radiance, and normalized water leaving radiance at 555 nm 0.15 Wm-2 sr-1 (McClain et al., 1995). '''Description of observation methods/instruments:''' Ocean colour technique exploits the emerging electromagnetic radiation from the sea surface in different wavelengths. The spectral variability of this signal defines the so called ocean colour which is affected by the presence of phytoplankton. By comparing reflectances at different wavelengths and calibrating the result against in-situ measurements, an estimate of chlorophyll content can be derived. '''Quality / Accuracy / Calibration information:''' Detailed description of cal/val is given in the relevant QUID, associated validation reports and quality documentation. '''Suitability, Expected type of users / uses:''' This product is meant for use for educational purposes and for the managing of the marine safety, marine resources, marine and coastal environment and for climate and seasonal studies. '''DOI (product) :''' https://doi.org/10.48670/moi-00101

'''This product has been archived''' For operationnal and online products, please visit https://marine.copernicus.eu '''Short description:''' For the Global Ocean- In-situ observation yearly delivery in delayed mode. The In Situ delayed mode product designed for reanalysis purposes integrates the best available version of in situ data for temperature and salinity measurements. These data are collected from main global networks (Argo, GOSUD, OceanSITES, World Ocean Database) completed by European data provided by EUROGOOS regional systems and national system by the regional INS TAC components. It is updated on a yearly basis. This version is a merged product between the previous verion of CORA and EN4 distributed by the Met Office for the period 1950-1990. '''DOI (product) :''' https://doi.org/10.17882/46219

'''This product has been archived''' "''DEFINITION''' Marine primary production corresponds to the amount of inorganic carbon which is converted into organic matter during the photosynthesis, and which feeds upper trophic layers. The daily primary production is estimated from satellite observations with the Antoine and Morel algorithm (1996). This algorithm modelized the potential growth in function of the light and temperature conditions, and with the chlorophyll concentration as a biomass index. The monthly area average is computed from monthly primary production weighted by the pixels size. The trend is computed from the deseasonalised time series (1998-2022), following the Vantrepotte and Mélin (2009) method. The trend estimate is not shown because the length of the time series does not allow to completely differentiate the climate trend to the natural variability of the primary production. More details are provided in the Ocean State Reports 4 (Cossarini et al. ,2020). '''CONTEXT''' Marine primary production is at the basis of the marine food web and produce about 50% of the oxygen we breath every year (Behrenfeld et al., 2001). Study primary production is of paramount importance as ocean health and fisheries are directly linked to the primary production (Pauly and Christensen, 1995, Fee et al., 2019). Changes in primary production can have consequences on biogeochemical cycles, and specially on the carbon cycle, and impact the biological carbon pump intensity, and therefore climate (Chavez et al., 2011). Despite its importance for climate and socio-economics resources, primary production measurements are scarce and do not allow a deep investigation of the primary production evolution over decades. Satellites observations and modelling can fill this gap. However, depending of their parametrisation, models can predict an increase or a decrease in primary production by the end of the century (Laufkötter et al., 2015). Primary production from satellite observations presents therefore the advantage to dispose an archive of more than two decades of global data. This archive can be assimilated in models, in addition to direct environmental analysis, to minimise models uncertainties (Gregg and Rousseaux, 2019). In the Ocean State Reports 4, primary production estimate from satellite and from modelling are compared at the scale of the Mediterranean Sea. This demonstrates the ability of such a comparison to deeply investigate physical and biogeochemical processes associated to the primary production evolution (Cossarini et al., 2020) '''CMEMS KEY FINDINGS''' Global primary production does not show specific trend and remain relatively constant over the archive 1998-2022. The temporal variability of the primary production appears to be mainly driven by the seasonal variation. However, some specific inter-annual event may induce noticeable increase or decrease in primary production, as for example in the second part of 2011. '''DOI (product):''' https://doi.org/10.48670/moi-00225

'''This product has been archived''' For operationnal and online products, please visit https://marine.copernicus.eu '''Short description:''' Global Ocean- Gridded objective analysis fields of temperature and salinity using profiles from the reprocessed in-situ global product CORA (INSITU_GLO_TS_REP_OBSERVATIONS_013_001_b) using the ISAS software. Objective analysis is based on a statistical estimation method that allows presenting a synthesis and a validation of the dataset, providing a validation source for operational models, observing seasonal cycle and inter-annual variability. '''DOI (product) :''' https://doi.org/10.48670/moi-00038

'''This product has been archived''' For operationnal and online products, please visit https://marine.copernicus.eu '''Short description:''' For the Global Ocean- Gridded objective analysis fields of temperature and salinity using profiles from the in-situ near real time database are produced monthly. Objective analysis is based on a statistical estimation method that allows presenting a synthesis and a validation of the dataset, providing a support for localized experience (cruises), providing a validation source for operational models, observing seasonal cycle and inter-annual variability. '''DOI (product) :''' https://doi.org/10.48670/moi-00037

'''This product has been archived''' For operationnal and online products, please visit https://marine.copernicus.eu '''Short description:''' For the European Ocean - Sea Surface Temperature Mono-Sensor L3 Observations. One SST file per 24h per area and per sensor (bias corrected) closest to the original resolution: SLSTR-A, AMSR2, SEVIRI, AVHRR_METOP_B, AVHRR18_G, AVHRR_19L, MODIS_A, MODIS_T, VIIRS_NPP. One SST file per file window per area and per sensor (bias corrected) closest to the original resolution , while still manageable in terms volume over the processed area. '''Description of observation methods/instruments:''' The METOP_B derived SSTs are not bias corrected because METOP_B is used as the reference sensor for the correction method. '''DOI (product) :''' https://doi.org/10.48670/moi-00162

'''This product has been archived''' For operationnal and online products, please visit https://marine.copernicus.eu '''Short description:''' For the Global Ocean- In-situ observation delivered in delayed mode. This In Situ delayed mode product integrates the best available version of in situ oxygen, chlorophyll / fluorescence and nutrients data '''DOI (product) :''' https://doi.org/10.17882/86207

'''DEFINITION''' Ocean heat content (OHC) is defined here as the deviation from a reference period (1993-2014) and is closely proportional to the average temperature change from z1 = 0 m to z2 = 700 m depth: OHC=∫_(z_1)^(z_2)ρ_0 c_p (T_yr-T_clim )dz [1] with a reference density of = 1030 kgm-3 and a specific heat capacity of cp = 3980 J kg-1 °C-1 (e.g. von Schuckmann et al., 2009). Time series of annual mean values area averaged ocean heat content is provided for the Mediterranean Sea (30°N, 46°N; 6°W, 36°E) and is evaluated for topography deeper than 300m. '''CONTEXT''' Knowing how much and where heat energy is stored and released in the ocean is essential for understanding the contemporary Earth system state, variability and change, as the oceans shape our perspectives for the future. The quality evaluation of MEDSEA_OMI_OHC_area_averaged_anomalies is based on the “multi-product” approach as introduced in the second issue of the Ocean State Report (von Schuckmann et al., 2018), and following the MyOcean’s experience (Masina et al., 2017). Six global products and a regional (Mediterranean Sea) product have been used to build an ensemble mean, and its associated ensemble spread. The reference products are: • The Mediterranean Sea Reanalysis at 1/24 degree horizontal resolution (MEDSEA_MULTIYEAR_PHY_006_004, DOI: https://doi.org/10.25423/CMCC/MEDSEA_MULTIYEAR_PHY_006_004_E3R1, Escudier et al., 2020) • Four global reanalyses at 1/4 degree horizontal resolution (GLOBAL_MULTIYEAR_PHY_ENS_001_031): GLORYS, C-GLORS, ORAS5, FOAM • Two observation based products: CORA (INSITU_GLO_PHY_TS_OA_MY_013_052) and ARMOR3D (MULTIOBS_GLO_PHY_TSUV_3D_MYNRT_015_012). Details on the products are delivered in the PUM and QUID of this OMI. '''CMEMS KEY FINDINGS''' The ensemble mean ocean heat content anomaly time series over the Mediterranean Sea shows a continuous increase in the period 1993-2022 at rate of 1.38±0.08 W/m2 in the upper 700m. After 2005 the rate has clearly increased with respect the previous decade, in agreement with Iona et al. (2018). '''DOI (product):''' https://doi.org/10.48670/moi-00261

'''This product has been archived''' For operationnal and online products, please visit https://marine.copernicus.eu '''Short description:''' The Global Ocean Satellite monitoring and marine ecosystem study group (GOS) of the Italian National Research Council (CNR), in Rome, distributes Level-4 product including the daily interpolated chlorophyll field with no data voids starting from the multi-sensor (MODIS-Aqua, NOAA-20-VIIRS, NPP-VIIRS, Sentinel3A-OLCI at 300m of resolution) (at 1 km resolution) and the monthly averaged chlorophyll concentration for the multi-sensor (at 1 km resolution) and Sentinel-OLCI Level-3 (at 300m resolution). Chlorophyll field are obtained by means of the Mediterranean regional algorithms: an updated version of the MedOC4 (Case 1 waters, Volpe et al., 2019, with new coefficients) and AD4 (Case 2 waters, Berthon and Zibordi, 2004). Discrimination between the two water types is performed by comparing the satellite spectrum with the average water type spectral signature from in situ measurements for both water types. Reference insitu dataset is MedBiOp (Volpe et al., 2019) where pure Case II spectra are selected using a k-mean cluster analysis (Melin et al., 2015). Merging of Case I and Case II information is performed estimating the Mahalanobis distance between the observed and reference spectra and using it as weight for the final merged value. The interpolated gap-free Level-4 Chl concentration is estimated by means of a modified version of the DINEOF algorithm by GOS (Volpe et al., 2018). DINEOF is an iterative procedure in which EOF are used to reconstruct the entire field domain. As first guess, it uses the SeaWiFS-derived daily climatological values at missing pixels and satellite observations at valid pixels. The other Level-4 dataset is the time averages of the L3 fields and includes the standard deviation and the number of observations in the monthly period of integration. '''Processing information:''' Multi-sensor products are constituted by MODIS-AQUA, NOAA20-VIIRS, NPP-VIIRS and Sentinel3A-OLCI. For consistency with NASA L2 dataset, BRDF correction was applied to Sentinel3A-OLCI prior to band shifting and multi sensor merging. Hence, the single sensor OLCI data set is also distributed after BRDF correction. Single sensor NASA Level-2 data are destriped and then all Level-2 data are remapped at 1 km spatial resolution (300m for Sentinel3A-OLCI) using cylindrical equirectangular projection. Afterwards, single sensor Rrs fields are band-shifted, over the SeaWiFS native bands (using the QAAv6 model, Lee et al., 2002) and merged with a technique aimed at smoothing the differences among different sensors. This technique is developed by The Global Ocean Satellite monitoring and marine ecosystem study group (GOS) of the Italian National Research Council (CNR, Rome). Then geophysical fields (i.e. chlorophyll, kd490, bbp, aph and adg) are estimated via state-of-the-art algorithms for better product quality. Level-4 includes both monthly time averages and the daily-interpolated fields. Time averages are computed on the delayed-time data. The interpolated product starts from the L3 products at 1 km resolution. At the first iteration, DINEOF procedure uses, as first guess for each of the missing pixels the relative daily climatological pixel. A procedure to smooth out spurious spatial gradients is applied to the daily merged image (observation and climatology). From the second iteration, the procedure uses, as input for the next one, the field obtained by the EOF calculation, using only a number of modes: that is, at the second round, only the first two modes, at the third only the first three, and so on. At each iteration, the same smoothing procedure is applied between EOF output and initial observations. The procedure stops when the variance explained by the current EOF mode exceeds that of noise. '''Description of observation methods/instruments:''' Ocean colour technique exploits the emerging electromagnetic radiation from the sea surface in different wavelengths. The spectral variability of this signal defines the so-called ocean colour which is affected by the pre+D2sence of phytoplankton. '''Quality / Accuracy / Calibration information:''' A detailed description of the calibration and validation activities performed over this product can be found on the CMEMS web portal. '''Suitability, Expected type of users / uses:''' This product is meant for use for educational purposes and for the managing of the marine safety, marine resources, marine and coastal environment and for climate and seasonal studies. '''Dataset names:''' *dataset-oc-med-chl-multi-l4-chl_1km_monthly-rt-v02 *dataset-oc-med-chl-multi-l4-interp_1km_daily-rt-v02 *dataset-oc-med-chl-olci-l4-chl_300m_monthly-rt-v02 '''Files format:''' *CF-1.4 *INSPIRE compliant '''DOI (product) :''' https://doi.org/10.48670/moi-00113

'''This product has been archived''' For operationnal and online products, please visit https://marine.copernicus.eu '''DEFINITION''' Marine primary production corresponds to the amount of inorganic carbon which is converted into organic matter during the photosynthesis, and which feeds upper trophic layers. The daily primary production is estimated from satellite observations with the Antoine and Morel algorithm (1996). This algorithm modelized the potential growth in function of the light and temperature conditions, and with the chlorophyll concentration as a biomass index. The monthly area average is computed from monthly primary production weighted by the pixels size. The trend is computed from the deseasonalised time series (1998-2019), following the Vantrepotte and Mélin method. More details are provided in the Ocean State Reports 4 (Cossarini et al. ,2020). '''CONTEXT''' Marine primary production is at the basis of the marine food web and produce about 50% of the oxygen we breath every year (Behrenfeld et al., 2001). Study primary production is of paramount importance as ocean health and fisheries are directly linked to the primary production (Pauly and Christensen, 1995, Fee et al., 2019). Changes in primary production can have consequences on biogeochemical cycles, and specially on the carbon cycle, and impact the biological carbon pump intensity, and therefore climate (Chavez et al., 2011). Despite its importance for climate and socio-economics resources, primary production measurements are scarce and do not allow a deep investigation of the primary production evolution over decades. Satellites observations and modelling can fill this gap. However, depending of their parametrisation, models can predict an increase or a decrease in primary production by the end of the century (Laufkötter et al., 2015). Primary production from satellite observations present therefore the advantage to dispose an archive of more than two decades of global data. This archive can be assimilated in models, in addition to direct environmental analysis, to minimise models uncertainties (Gregg and Rousseaux, 2019). In the Ocean State Reports 4, primary production estimate from satellite and from modelling are compared at the scale of the Mediterranean Sea. This demonstrate the ability of such a comparison to deeply investigate physical and biogeochemical processes associated to the primary production evolution (Cossarini et al., 2020) '''CMEMS KEY FINDINGS''' The trend for the global ocean is negative over the period 1998-2019 with a decline in primary production of about 0.67 mgC.m-2.yr-1 or equivalently 0.2 %.yr-1. Note: The key findings will be updated annually in November, in line with OMI evolutions. '''DOI (product):''' https://doi.org/10.48670/moi-00225